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Diamond Vogel High Solids Miracle Glaze Urethane-Old Product
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/Canada
Purpose of product.
Usage:Structure such as solid, liquid, aerosol etc.
Form: liquidDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 15, 20241110 Albany Place SE
Orange City IA 51041
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
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The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.REACH COMPLIANCE
EU Hazard Classification Directive 67/548/EECHazard Symbols are used to classify dangerous substances.
Hazard SymbolsRisk Phrases, denoted as a series of numbers preceded by the letter "R" indicate the nature of the special risks, in accordance with Annex III to Directive 67/548/EEC (see Article 23(2)(d) Directive 67/548/EEC). The numbers are separated by either a comma to denote separate statements concerning special risks, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the special risks.
Risk PhrasesSafety Phrases, denoted as a series of numbers preceded by the letter "S" indicating the recommended safety precautions, in accordance with Annex IV to Directive 67/548/EEC. The numbers are separated by either a comma to denote separate statements concerning safety precautions, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the safety precautions.
Safety PhrasesSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).-- 001330-20-7 -- 20.0-50.0 -- -- -- -- 000100-41-4 -- 5.0-20.0 F, Xn -- -- -- -- 000584-84-9 -- 20.0-50.0 -- -- -- Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.2
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.California Prop.65 Chemical?The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
UN Global Harmonization Classification
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Endocrine Disruptor (ED)Xylene (mixed isomers)
001330-20-7
215-535-720.0-50.0 No H226, H312, H332, H315 P210, P243, P260, P280, P303+P361+P353, P332+P313 No No Ethylbenzene
000100-41-4
202-849-45.0-20.0 Yes H225, H332 P201, P202, P210, P233, P240, P241, P242, P243, P260, P261, P271, P280, P281, P303+P361+P353, P304+P340, P308+P313, P312, P314, P370+P378, P403+P235, P405, P501 No No Toluene 2,4-diisocyanate
000584-84-9
209-544-520.0-50.0 No H351, H330, H319, H335, H315, H334, H317, H412 P273, P280, P284, P308+P313, P403+P233, P501 No No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Hazard Statements
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- Code
- Statement
- H225 : Highly flammable liquid and vapourH226 : Flammable liquid and vapourH312 : Harmful in contact with skinH315 : Causes skin irritationH317 : May cause an allergic skin reactionH319 : Causes serious eye irritationH330 : Fatal if inhaledH332 : Harmful if inhaledH334 : May cause allergy or asthma symptoms or breathing difficulties if inhaledH335 : May cause respiratory irritationH351 : Suspected of causing cancerH412 : Harmful to aquatic life with long lasting effects
- P201 : Obtain special instructions before useP202 : Do not handle until all safety precautions have been read and understoodP210 : Keep away from heat/sparks/open flames/hot surfacesP233 : Keep container tightly closedP240 : Ground/bond container and receiving equipmentP241 : Use explosion-proof electrical/ventilating/light/…/equipmentP242 : Use only non-sparking toolsP243 : Take precautionary measures against static dischargeP260 : Do not breathe dust/fume/gas/mist/vapours/sprayP261 : Avoid breathing dust/fume/gas/mist/vapours/sprayP271 : Use only outdoors or in a well-ventilated areaP273 : Avoid release to the environmentP280 : Wear protective gloves/protective clothing/eye protection/face protectionP281 : Use personal protective equipment as requiredP284 : Wear respiratory protectionP312 : Call a POISON CENTER or doctor/physician if you feel unwellP314 : Get Medical advice/attention if you feel unwellP303+P361+P353 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/showerP304+P340 : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingP308+P313 : If exposed or concerned: Get medical advice/attentionP332+P313 : If skin irritation occurs: Get medical advice/attentionP370+P378 : In case of fire: Use … for extinctionP405 : Store locked upP501 : Dispose of contents/container to
- GHS02 : FlammableGHS06 : ToxicGHS07 : IrritantGHS08 : Health Hazard
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Material Safety Data Sheet(MSDS) Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product.
MSDS DATE :July 14, 2004 -
SVHC declaration
This product does not contain any Substances of Very High Concern (SVHC).
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Warnings
MSDS: WARNING MESSAGES: (1) Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Chronic exposure may cause damage to the central nervous system, respiratory system, lung, eye, skin, liver, gastrointestinal tract, spleen, kidneys, and blood. From Description *WARNING! If you scrape, sand, or remove old paint, you may release lead dust. LEAD IS TOXIC. EXPOSURE TO LEAD DUST CAN CAUSE SERIOUS ILLNESS, SUCH AS BRAIN DAMAGE, ESPECIALLY IN CHILDREN. PREGNANT WOMEN SHOULD ALSO AVOID EXPOSURE. Wear a NIOSH-approved respirator to control lead exposure. Clean up carefully with a HEPA vacuum and wet mop. Before you start, find out how to protect yourself and your family by contacting the national Lead Information Hotline at 1-800-424-LEAD or log on to www.epa.gov/lead. -
Acute health effects
From MSDS EFFECTS OF OVEREXPOSURE: Odor Threshold- There is no available information on the polymeric isocyanate. The odor threshold for Toluene 2,4-diisocyanate is 0.17 ppm. TDI is considered to have a poor warning properties, that is if you can smell it, then it is above the recommended occupational standards for the compound. Irritation Threshold- The irritation threshold for this product has not been clearly established because those persons sensitized to TDI may show signs and symptoms of irritation at levels far below those that are not sensitized. Inhalation- Acute: Exposure may cause mucous membrane and respiratory tract irritation, tightness of chest, headache, shortness of breath, and a dry cough. Inhalation may cause headaches, drowsiness, unconsciousness, anesthesia and asthma-like symptoms to occur. These symptoms may include coughing, wheezing, and shortness of breath. A hypersensitive pneumonitis may also occur if the person is sensitized. This syndrome is characterized by fever, nonproductive cough, wheezing, chills, and shortness of breath. The effects of acute exposure may be delayed in onset up to 12-24 hours. Chronic: Repeated exposure may cause an allergic sensitization of the respiratory tract. This is characterized by an asthma-like response upon re-exposure to the chemical. The symptoms may include coughing, wheezing, shortness of breath and chest tightness. Repeated overexposure to isocyanates and high one-time accidental exposures to isocyanates have been associated with a gradual decrease in lung volume (lung damage). Skin- Acute: If not properly removed, liquid spills of TDI on the skin may cause irritation, redness, swelling, blistering or burns. Chronic: Repeated contact may cause irritation of the skin and an allergic skin reaction consisting of a hive-like rash on locations not even directly contacted by the liquid. Animal studies indicate that dermal exposure to TDI may induce an allergic sensitization of the respiratory tract as well. This is characterized by an asthma-like response which may include coughing, wheezing, shortness of breath, chest tightness, and may be fatal. Eye- The effects of liquid directly contacting the eye can be significant. This may result in severe irritation and possible damage to the cornea and impairment of vision. The effects of high vapor concentrations may vary from slight irritation with tearing and burning sensation to keratitis consisting of inflammation of the cornea and impairment of vision. Ingestion- Acute: Can result in irritation of the mouth, stomach tissue and digestive tract. Gastroenteritis may result with any or all of the following symptoms; nausea, vomiting diarrhea, headache. Small amounts aspirated into the lungs during ingestion or vomiting may cause mild to severe pulmonary injury and possibly death. Chronic: More pronounced gastroenteritis effects would probably occur if this material was repeatedly ingested. Target organ toxicity- Irritation to the skin, eyes, mucous membrane, and respiratory tract. Reproductive and developmental toxicity- TDI is not known or reported to be a developmental or reproductive toxin. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Asthma, Chronic respiratory disease (e.g. Bronchitis, Emphysema) Eye disease, Skin disorders and Allergies. PRIMARY ROUTE(S) OF ENTRY: Inhalation, skin contact, skin absorption & eye contact. -
Chronic health effects
From MSDS Refer to Acute Health -
Carcinogenicity
From MSDS Carcinogenicity- TDI is reported to be carcinogenic by the following agencies: IARC, NTP. These determinations have LG-0414 4 been based on the following information. TDI isocyanate has been shown to cause cancer in laboratory animals when administered orally at high dose levels in corn oil. This study was conducted under the auspices of the US National Toxicology Program. It has been postulated that the positive results (tumor formation) in this study may have been caused by the hydrolysis of TDI to TDA, a known carcinogen. The relevant route of industrial exposure to this product is through inhalation. Other studies, sponsored by the International Isocyanate Institute have shown that TDI does not produce cancer when administered to laboratory animals via inhalation. The dose levels in the inhalation studies were significantly lower than those of the studies in which TDI given orally in corn oil, and TDI is not hydrolyzed to TDA when administered via the inhalation route of exposure. The route of exposure and level of dose used on the inhalation work reflect more accurately the conditions of industrial exposure. Based on the lack of carcinogenic response in animals from inhalation of TDI, the manufacturer of the TDI judges that the risk of cancer in humans from industrial use of this substance is not significant. Xylene contains ethylbenzene which has been classified as a possible carcinogen to humans, Class 2B, by the International Agency for Research of Cancer (IARC), based on sufficient evidence in laboratory animals but inadequate evidence for cancer in humans. Prolonged or repeated overexposure to ethylbenzene may cause the following: kidney effects, liver effects, lung effects, thyroid effects, testicular effects, pituitary effects. Mutagenicity- TDI has produced both positive and negative results in the Ames Salmonella gene mutation assay. A positive result may have been caused by hydrolysis of the TDI to TDA, a know mutagen. Other in vitro test systems have also reported positive results, also probably due to the water-TDI interaction. In vivo (whole animal studies) have reported negative results. A micronucleus assay to measure chromosomal effects potential was performed in conjunction with the two year rat inhalation study showed negative results. An unscheduled DNA synthesis assay conducted dosing the animals in vivo also showed TDI not to be mutagenic under this system's conditions. The significance of all these tests for human health is unclear other then to conclude that TDI is a reactive chemical and has some possible significant biological activity. -
Handling information
From MSDS Keep away from heat. Keep away from sparks, flames and other sources of ignition. Store in a cool, dry place. Keep container closed when not in use. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use with adequate ventilation. Ground and bond containers when transferring material. Use explosion proof equipment. Follow all MSDS/label precautions even after the container is emptied because it may retain product residues. Wash thoroughly after handling. OTHER PRECAUTIONS: Avoid resealing containers that have been contaminated with water. The resulting reaction could cause a pressure within the container which is great enough to burst the container. -
Disposal information
From MSDS Waste must be disposed of in accordance with federal, state and local environmental control regulations. Incineration is the preferred method. Empty containers must be handled with care due to product residue. Decontaminate prior to disposal. DO NOT HEAT OR CUT EMPTY CONTAINER WITH ELECTRIC OR GAS TORCH. -
First Aid
From MSDS EYES- Immediately flush with large amounts of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Call a physician at once. SKIN- Immediately flush with water for 15 minutes. Wash the contaminated skin with soap and water. If irritation develops, call a physician. If clothing comes in contact with the product, the clothing should be laundered before reuse. INGESTION- Immediately drink large quantities of water. DO NOT induce vomiting. Call a physician at once. DO NOT give anything by mouth if the person is unconscious or if having convulsions. INHALATION- If person experiences nausea, headache or dizziness, person should stop work immediately and move to fresh air until these symptoms disappear. If breathing is difficult, administer oxygen, keep the person warm and at rest. Call a physician. In the event that an individual inhales enough product to lose consciousness, person should be moved to fresh air at once and a physician should be called immediately. If breathing has stopped, artificial respiration should be given immediately. In all cases, ensure adequate ventilation and provide respiratory protection before the person returns to work.
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