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CPID

Health effects of consumer products

Ortho Home Orchard Spray-Old Product

• Chemical Composition/Ingredients

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

  Advanced
  Primary Chemical Name is the standard name assigned to a chemical substance. Chemical	Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.  CAS No./ID	Percent of chemical in preparation. % Conc.		Chemical of Concern (CoC) Chemical of Concern(CoC)
  Captan	000133-06-2	14 .7		Yes  NY-01: California Prop. 65 Chemical NY-17: California Toxic Air Contaminant Chemicals (TACs) NY-20:CA Environmental Biocontaminant Monitoring Program Priority Chemical CA-01-California Prop. 65 Chemicals CA-18-California Toxic Air Contaminant Chemicals (TACs) CA-21-California Environmental Biocontaminant Monitoring Program Priority Chemicals MN-01-Minnesota Toxic Free Kids, CHC  CoC List
  Malathion	000121-75-5	7.5		Yes  NY-01: California Prop. 65 Chemical NY-04: EPA-IRIS, Neurotoxicity Reference Dose Chemical NY-08: IARC Group 1, 2A & 2B Carcinogens NY-09: ATSDR Neurotoxicants NY-20:CA Environmental Biocontaminant Monitoring Program Priority Chemical CA-01-California Prop. 65 Chemicals CA-04: EPA-IRIS, Neurotoxicity Reference Dose Chemical CA-09-IARC Group 1, 2A & 2B Carcinogen CA-10: ATSDR Neurotoxicants CA-21-California Environmental Biocontaminant Monitoring Program Priority Chemicals MN-01-Minnesota Toxic Free Kids, CHC  CoC List
  Methoxychlor	000072-43-5	15		Yes  NY-10: EPA Waste Management Program PB&T Priority Chemical NY-12: EPA Toxic Release Inventory (TRI) PB&T Chemical NY-16: California Title 22 Chemical Exceeding MCLs NY-17: California Toxic Air Contaminant Chemicals (TACs) NY-20:CA Environmental Biocontaminant Monitoring Program Priority Chemical NY-26: New York DOH MCL CA-11: EPA Waste Management Program PB&T Priority Chemical CA-13-EPA Toxic Release Inventory (TRI) PB&T Chemicals CA-17-California Title 22 Chemicals Exceeding MCLs CA-18-California Toxic Air Contaminant Chemicals (TACs) CA-21-California Environmental Biocontaminant Monitoring Program Priority Chemicals CA-22-OSPAR Conventions for Protection of Marine Environment of North-East Atlantic, Priority Chemicals MN-01-Minnesota Toxic Free Kids, CHC NY-28: New York Air Toxics Ny-21: OSPAR Priority Chemicals  CoC List
  Inert ingredients (unspecified)	999999-00-2	62.8		No
  Kaolin clay	001332-58-7	--		No
  Kieselguhr	061790-53-2	--		No
  Magnesium carbonate	000546-93-0	--		No
  Silica, amorphous (Diatomaceous silica)	007631-86-9	--		No
   
  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID headings to sort values.
  

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers. 

  CAS No./ID

  Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
  EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
  ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
  NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-x

  EC No.

  Percent of chemical in preparation.

  % Conc.

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

   UN Global Harmonization Classification

  Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:

  • Physical Hazard Codes (H200 series)
  • Health Hazard Codes (H300 series)
  • Environmental Hazard Codes (H400 series)
  • Supplementary Hazard Codes (EUH series)

  Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Hazard Statement Code

  Precautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
  Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Precautionary Code

  Pictogram

  SVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
  1.  Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
  2.  Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
  3.  Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).

  SVHC?

  Captan	000133-06-2	205-087-0	14 .7	H331, H318, H317, H351, H400 P261, P271, P273, P280, P305+P351+P338, P310, P321, P501 No
  Malathion	000121-75-5	204-497-7	7.5	H302, H317, H400, H410 ------- No
  Methoxychlor	000072-43-5	200-779-9	15	-------- ------- ---- No
  Inert ingredients (unspecified)	999999-00-2	--	62.8	-------- ------- ---- No
  Kaolin clay	001332-58-7	310-194-1	--	-------- ------- ---- No
  Kieselguhr	061790-53-2	--	--	-------- ------- ---- No
  Magnesium carbonate	000546-93-0	208-915-9	--	-------- ------- ---- No
  Silica, amorphous (Diatomaceous silica)	007631-86-9	231-545-4	--	-------- ------- ---- No

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID or EC No. headings to sort values.
  

   

  Sources for Chemical Classifications

  • European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
  • European Chemicals Agency, http://echa.europa.eu/
       ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
• • Health Effects Information

    • Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.

    • Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product. MSDS DATE :

      October 24, 1996

    • 	Health	Flammability	Reactivity
      HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product. HMIS RATING	2	0	0

    • Warnings

      CAUSES IRREVERSIBLE EYE DAMAGE - DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING - HARMFUL IF SWALLOWED - MAY CAUSE AN ALLERGIC SKIN REACTION - KEEP OUT OF REACH OF CHILDREN FIRST AID MEASURES EYES: Immediately hold eyelids open and flush eyes with fresh water for at least 15 minutes. Remove contact lenses if worn. Get medical attention immediately. SKIN: No first aid procedures are required. As a precaution, wash skin thoroughly with soap and water. Remove and wash contaminated clothing. INGESTION: If swallowed, give water or milk to drink and telephone for medical advice. Consult medical personnel before inducing vomiting. If medical advice cannot be obtained, then take the person and product container to the nearest medical emergency treatment center or hospital. INHALATION: If respiratory discomfort or irritation occurs, move the person to fresh air. See a doctor if discomfort or irritation continues. NOTES TO PHYSICIAN: This material contains a cholinesterase inhibitor. Measurement of blood cholinesterase activity may be useful in monitoring exposure. If signs of cholinesterase inhibition appear, atropine sulfate is antidotal. 2-PAM (PROTOPAM) is also antidotal and may be used in conjunction with atropine but should not be used alone. ADDITIONAL INFORMATION: Medical Information: Call day or night, 1-800-454-2333.

    • Acute health effects

      From MSDS POTENTIAL HEALTH EFFECTS EYES: This substance is a severe eye irritant and could cause permanent damage to your eyes and blindness. The degree of the injury will depend on the amount of material that gets into the eye and the speed and thoroughness of the first aid treatment. Symptoms of overexposure may include discomfort, irritation and redness, and blurred vision. SKIN: This substance is not expected to cause prolonged or significant skin irritation. If absorbed through the skin, this substance is considered practically non-toxic to internal organs. See Toxicological Information, section 11. INGESTION: This substance is slightly toxic to internal organs if swallowed. The degree of injury will depend on the amount absorbed from the gut. INHALATION: Breathing the vapor may be irritating to the respiratory tract. If inhaled, this substance is considered practically non-toxic to internal organs. Read the Toxicological Information section (11) of this document for more information.

    • Chronic health effects

      From MSDS NEUROTOXICITY: Malathion has not demonstrated the potential to produce organophosphate induced delayed neuropathy. Results of chicken neurotoxicity studies were negative. TERATOGENICITY: There are no scientific findings or results of teratology studies that support the components in this product causing birth defects. Captan has been studied in 4 species including the monkey, for a total of 17 investigations. REPRODUCTIVE TOXIN: The components in this product are not considered to be reproductive toxins. Results of both one and three generation Captan rat reproduction studies were negative. The NOEL's for the two studies regarding systemic toxicity was 12.5 mg/kg/dy. MUTAGENICITY: The components in this product are not considered to be mutagens. GENERAL COMMENTS: This product contains an organic phosphorus insecticide which inhibits the enzyme cholinesterase. Signs and symptoms which may be seen, usually within 12 hours following overexposure, may include, but may not be limited to, headache, dizziness, weakness, constriction of the pupil of the eye, blurred or dark vision, excessive salivation or nasal discharge, profuse sweating, abdominal cramps, nausea and vomiting. Incontinence, unconsciousness and convulsions indicate severe poisoning. In untreated severe poisoning, respiratory depression or cardiac arrest may be fatal. Repeated exposure may result in depletion of cholinesterase. Additional slight exposure may result in signs and symptoms. Note to Physician: Measurement of blood cholinesterase activity may be useful in monitoring exposure. If signs of cholinesterase inhibition appear, atropine sulfate is antidotal. 2-PAM (PROTOPAM) is also antidotal and may be used in conjunction with atropine but should not be used alone. This product contains an organochlorine insecticide. Chronic intoxication following prolonged or continued exposures may result in fainting, muscle spasms, tremors, or loss of weight.

    • Carcinogenicity

      From MSDS CARCINOGENICITY COMMENTS: There is no evidence to support that the components in this product are carcinogens. Although the product contains Captan, results of a lifetime feeding study demonstrated an increased incidence in intestinal tumors when the chemical was fed in the daily lifetime diet of mice at high dose levels of 6,000 and 16,000 ppm. The dose of Captan had to be sufficient to overwhelm the animals' detoxification mechanism. It is important to note that mammals rapidly detoxify Captan, such that ingestion of low dietary dose levels would not be absorbed into the systemic circulation. Results of three rat chronic investigations were negative when Captan was administered in the daily diet at dose levels of 2,000 ppm. Methoxychlor and malathion were negative in the toxicology chronic feeding studies.

    • Handling information

      From MSDS GENERAL PROCEDURES: Keep pesticide in original container. Do not put concentrate or dilute into food or drink containers. Avoid contamination of feed, foodstuffs. Store in a cool dry place, preferably in a locked storage area. Do not store diluted spray. ENVIRONMENTAL DATA: No data available. ECOTOXICOLOGICAL INFORMATION: This pesticide is toxic to fish, aquatic invertebrates, and aquatic life stages of amphibians. Do not apply directly to water. Drift and runoff may be hazardous to aquatic organisms in areas near the application site. Do not contaminate water when disposing of equipment washwaters. This product is highly toxic to bees exposed to direct treatment on blooming crops or weeds. Do not apply this product or allow it to drift to blooming crops or weeds if bees are visiting the treatment area.

    • Disposal information

      From MSDS The Solaris Group is committed to responsible environmental practices and recommends that all of the product be used up, carefully following all label directions and precautions. If necessary to dispose of partially filled product container, then securely wrap it in several layers of newspaper and discard in trash. EMPTY CONTAINER: Do not reuse empty container. Discard container in trash.