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CPID

Health effects of consumer products

Bonide Complete Rose Spray II-Old Product

• Chemical Composition/Ingredients

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

  Back

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers. 

  CAS No./ID

  Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
  EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
  ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
  NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-x

  EC No.

  Percent of chemical in preparation.

  % Conc.

  REACH COMPLIANCE
  EU Hazard Classification Directive 67/548/EEC

  Hazard Symbols are used to classify dangerous substances.

  Hazard Symbols

  Risk Phrases, denoted as a series of numbers preceded by the letter "R" indicate the nature of the special risks, in accordance with Annex III to Directive 67/548/EEC (see Article 23(2)(d) Directive 67/548/EEC). The numbers are separated by either a comma to denote separate statements concerning special risks, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the special risks.

  Risk Phrases

  Safety Phrases, denoted as a series of numbers preceded by the letter "S" indicating the recommended safety precautions, in accordance with Annex IV to Directive 67/548/EEC. The numbers are separated by either a comma to denote separate statements concerning safety precautions, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the safety precautions.

  Safety Phrases

  SVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
  1.  Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
  2.  Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
  3.  Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).

  SVHC?

  --	000133-06-2	--	11.76	Carc. Cat. 3, T, Xi, N	--	--	--
  --	000121-75-5	--	6	Xn, N	--	--	--
  --	000072-43-5	--	12		--	--	--
  --	000063-25-2	--	0.3	Carc. Cat. 3, Xn, N	--	--	--

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID or EC No. headings to sort values.
  

   

  Sources for Chemical Classifications

  • European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.2
  • European Chemicals Agency, http://echa.europa.eu/
       ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers. 

  CAS No./ID

  Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
  EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
  ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
  NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-x

  EC No.

  Percent of chemical in preparation.

  % Conc.

  California Prop.65 Chemical?

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

   UN Global Harmonization Classification

  Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:

  • Physical Hazard Codes (H200 series)
  • Health Hazard Codes (H300 series)
  • Environmental Hazard Codes (H400 series)
  • Supplementary Hazard Codes (EUH series)

  Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Hazard Statement Code

  Precautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
  Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Precautionary Code

  Pictogram

  SVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
  1.  Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
  2.  Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
  3.  Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).

  SVHC?

  Endocrine Disruptor (ED)

  Captan
  000133-06-2 205-087-0	11.76	Yes	H331, H318, H317, H351, H400 P261, P271, P273, P280, P305+P351+P338, P310, P321, P501 No No
  Malathion
  000121-75-5 204-497-7	6	Yes	H302, H317, H400, H410 -- No No
  Methoxychlor
  000072-43-5 200-779-9	12	No	-- -- -- No No
  Carbaryl
  000063-25-2 200-555-0	0.3	Yes	H351, H332, H302, H400 -- No No

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID or EC No. headings to sort values.
  

   

  Sources for Chemical Classifications

  • European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
  • European Chemicals Agency, http://echa.europa.eu/
       ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
• • Hazard Statements

    • • Code
      • Statement
    • H302 : Harmful if swallowed
      H317 : May cause an allergic skin reaction
      H318 : Causes serious eye damage
      H331 : Toxic if inhaled
      H332 : Harmful if inhaled
      H351 : Suspected of causing cancer
      H400 : Very toxic to aquatic life
      H410 : Very toxic to aquatic life with long lasting effects
    • P261 : Avoid breathing dust/fume/gas/mist/vapours/spray
      P271 : Use only outdoors or in a well-ventilated area
      P273 : Avoid release to the environment
      P280 : Wear protective gloves/protective clothing/eye protection/face protection
      P310 : Immediately call a POISON CENTER or doctor/physician
      P321 : Specific treatment (see … on this label)
      P305+P351+P338 : IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do
      P501 : Dispose of contents/container to
    • GHS05 : Corrosive
      GHS06 : Toxic
      GHS07 : Irritant
      GHS08 : Health Hazard
      GHS09 : Environmentally Hazardous
  • Health Effects Information

    • Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.

    • Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product. MSDS DATE :

      November 30, 1998

    • Date when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified. MSDS Verified :

      January 02, 2008

    • 	Health	Flammability	Reactivity
      HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product. HMIS RATING	2	2	0

    • SVHC declaration

      This product does not contain any Substances of Very High Concern (SVHC).

    • Warnings

      DANGER

    • Acute health effects

      From MSDS
      PRIMARY ROUTES OF ENTRY: Skin, eye, inhalation, ingestion

      SIGNS & SYMPTOMS OF EXPOSURE: Two of the active ingredients, Sevin and malathion, are cholinesterase inhibitors. May cause eye and/or skin irritation. Vapors may irritate eyes. Prolonged skin and/or eye contact may result in material being absorbed in harmful amounts. Single dose oral toxicity is moderate; however, ingestion of larger amounts may cause serious injury. Inhalation of excessive amounts may cause upper respiratory tract irritation. Symptoms include headaches, dizziness, incoordination, drowsiness and unconsciousness.

      MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Any disease, medication or prior exposure which reduces normal cholinesterase activity may increase the susceptibility to the toxic effects of the active ingredients. Pre-existing skin, eye, liver, kidney, nervous system or respiratory disorders may be aggravated by excessive overexposure. Skin irritation may be aggravated in persons with existing skin lesions. Overexposure may aggravate existing chronic cardiovascular or respiratory disease, leading to respiratory difficulty, pulmonary edema and cyanosis. Exposure to cholinesterase inhibitors should be restricted in persons with hemolytic anemias or pre-existing cholinesterase inhibition.

    • Chronic health effects

      From MSDS
      Repeated exposures to cholinesterase inhibitors may, without warning, cause increased susceptibility to doses of any other cholinesterase inhibitor. Kidney and liver damage is possible from exposure to xylenes over long periods of time.

    • Carcinogenicity

      Not listed as carcinogen by IARC, NTP and OSHA.

    • Handling information

      Avoid excess heat, sparks, open flame or other ignition sources. Do not take internally. Avoid breathing vapors or spray mist. Avoid contact with skin, eyes & clothing. Wash thoroughly after handling. Do not contaminate water by disposal of equipment washwaters. Store in a cool, dry area out of reach of children and animals. Avoid sources of ignition.

    • Disposal information

      Dispose according to EPA procedures as outlined in RCRA. Follow local and state requirements. This product is toxic to fish, bees, aquatic and estuarine invertebrates, aquatic life stages of amphibians.

    • First Aid

      If known exposure occurs or if poisoning is suspected, DO NOT WAIT FOR SYMPTOMS TO DEVELOP. Immediately start the procedures recommended below and simultaneously contact a Poison Control Center, a physician or the nearest hospital, inform the person contacted of the type and extent of exposure, describe the victim's symptoms, and follow the advice given.
      SKIN: Wash the material off the skin with plenty of soap and water. If redness, itching or a burning sensation develops, get medical attention. Wash any contaminated clothing and decontaminate footwear before reuse.
      EYES: Immediately flush eyes with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Have eyes examined and treated by medical personnel as soon as possible.
      INGESTION: Do not induce vomiting. Aspiration hazard exists if swallowed or if vomiting occurs; product can enter lungs and cause damage. Call a physician or Poison Control Center immediately.
      INHALATION: Remove victim to fresh air. Contact medical personnel if a cough or other respiratory symptoms develop. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is labored, give oxygen. Consult medical personnel.
      NOTES TO PHYSICIAN: Contains an aromatic petroleum solvent, vomiting may cause aspiration pneumonia. Product also contains two active ingredients, which are cholinesterase inhibitors affecting the central and peripheral nervous systems and producing cardiac and respiratory depression. Atropine sulfate in large doses is an antidote. Two to four mg intravenously or intramuscularly as soon as cyanosis is overcome. Repeat at 5 to 10 minute intervals until signs of atropinization appear. 2-PAM chloride is a pharmacological antidote. DO NOT GIVE MORPHINE OR TRANQUILIZER