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HTH Spa Shock-Old Product
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: Spa Water TreatmentStructure such as solid, liquid, aerosol etc.
Form: granulesDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: March 20, 20201200 Bluegrass Lakes Parkway
Alpharetta GA 30004
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
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The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.REACH COMPLIANCE
EU Hazard Classification Directive 67/548/EECHazard Symbols are used to classify dangerous substances.
Hazard SymbolsRisk Phrases, denoted as a series of numbers preceded by the letter "R" indicate the nature of the special risks, in accordance with Annex III to Directive 67/548/EEC (see Article 23(2)(d) Directive 67/548/EEC). The numbers are separated by either a comma to denote separate statements concerning special risks, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the special risks.
Risk PhrasesSafety Phrases, denoted as a series of numbers preceded by the letter "S" indicating the recommended safety precautions, in accordance with Annex IV to Directive 67/548/EEC. The numbers are separated by either a comma to denote separate statements concerning safety precautions, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the safety precautions.
Safety PhrasesSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).-- 000471-34-1 -- 0-4 -- -- -- -- 007647-14-5 -- 5.0-15.0 -- -- -- -- 007732-18-5 -- 17-22 -- -- -- -- 007778-54-3 -- 40-55 O, C, Xn, N -- -- -- -- 010137-74-3 -- 0-4 -- -- -- -- 010043-52-4 -- 0-4 Xi -- -- -- -- 001305-62-0 -- 0-5 -- -- -- -- 010034-99-8 -- 25-35 -- -- -- Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.2
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.California Prop.65 Chemical?The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
UN Global Harmonization Classification
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Endocrine Disruptor (ED)Calcium carbonate
000471-34-1
207-439-90-4 No -- -- -- No No Sodium chloride
007647-14-5
231-598-35.0-15.0 No -- -- -- No No Water
007732-18-5
231-791-217-22 No -- -- -- No No Calcium hypochlorite
007778-54-3
231-908-740-55 No H272, H302, H314, H400, EUH031 P210, P220, P221, P280, P264, P270, P260, P273, P370+P378, P301+P312, P330, P301+P330+P331, P303+P361+P353, P363, P304+P340, P310, P321, P305+P351+P338, P391, P405, P501 No No Calcium chlorate
010137-74-3
--0-4 No -- -- -- No No Calcium chloride anhydrous
010043-52-4
233-140-80-4 No H319 P264, P280, P305+P351+P338, P337+P313 No No Calcium hydroxide
001305-62-0
215-137-30-5 No H315, H318, H335 P102, P280, P305, P351, P310, P302+P352, P261, P304+P340, P501 No No Magnesium sulfate heptahydrate
010034-99-8
--25-35 No -- -- -- No No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Hazard Statements
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- Code
- Statement
- H272 : May intensify fire; oxidizerH302 : Harmful if swallowedH314 : Causes severe skin burns and eye damageH315 : Causes skin irritationH318 : Causes serious eye damageH319 : Causes serious eye irritationH335 : May cause respiratory irritationH400 : Very toxic to aquatic lifeEUH031 : Contact with acids liberates toxic gas
- P102 : Keep out of reach of childrenP210 : Keep away from heat/sparks/open flames/hot surfacesP220 : Keep/Store away from clothing/…/combustible materialsP221 : Take any precaution to avoid mixing with combustibles…P260 : Do not breathe dust/fume/gas/mist/vapours/sprayP261 : Avoid breathing dust/fume/gas/mist/vapours/sprayP264 : Wash … thoroughly after handlingP270 : Do not eat, drink or smoke when using this productP273 : Avoid release to the environmentP280 : Wear protective gloves/protective clothing/eye protection/face protectionP305 : IF IN EYES:P310 : Immediately call a POISON CENTER or doctor/physicianP321 : Specific treatment (see … on this label)P330 : Rinse mouthP351 : Rinse continuously with water for several minutesP363 : Wash contaminated clothing before reuseP391 : Collect spillageP301+P312 : IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwellP301+P330+P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomitingP302+P352 : IF ON SKIN: Wash with soap and waterP303+P361+P353 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/showerP304+P340 : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingP305+P351+P338 : IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to doP337+P313 : Get medical advice/attentionP370+P378 : In case of fire: Use … for extinctionP405 : Store locked upP501 : Dispose of contents/container to
- GHS03 : OxidiserGHS05 : CorrosiveGHS07 : IrritantGHS09 : Environmentally Hazardous
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Material Safety Data Sheet(MSDS) Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product.
MSDS DATE :September 08, 2010 Date when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
MSDS Verified :April 13, 2011 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATING3 0 1 -
SVHC declaration
This product does not contain any Substances of Very High Concern (SVHC).
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Acute health effects
From MSDS:
Hazards Identification
Emergency Overview: Toxic by inhalation. Corrosive to eyes and skin, Lung toxin.
Routes of Entry: Inhalation, skin, eyes, ingestion
Potential Health Effects
Inhalation: Harmful if product is inhaled in high concentrations. Causes burns to respiratory tract. Inhalation of dust or vapor from this product can be irritating to the nose, mouth, throat and lungs. In confined areas, mechanical agitation can result in high levels of dust, and reaction with incompatible materials can result in high concentrations of chlorine vapor, either of which may result in burns to the respiratory tract, producing lung edema, shortness of breath, wheezing, choking, chest pains, impairment of lung function and possible permanent lung damage.
Skin contact: Dry material causes moderate skin irritation. Wet material causes skin burns. Dermal exposure to dry material causes moderate skin irritation characterized by redness and swelling. Dermal exposure to wet material can cause severe irritation and/or burns characterized by redness, swelling and scab formation. Prolonged skin exposure may cause permanent damage.
Eye contact: Causes burns to eyes. Severe irritation and/or burns can occur following eye exposure. Direct contact may cause impairment of vision and corneal damage.
Ingestion: Moderately toxic if swallowed. Causes burns to digestive tract. Irritation and/or burns can occur to the entire gastrointestinal tract, including the stomach and intestines, characterized by nausea, vomiting, diarrhea, abdominal pain, bleeding, and/or tissue ulceration or perforation. Significant exposure to this material can lead to serious health effects and/or death.
Medical Conditions Aggravated: Asthma, respiratory and cardiovascular disease. -
Chronic health effects
From MSDS:
Inhalation: Repeated inhalation exposure may cause impairment of lung function and permanent lung damage.
Skin Contact: Effects similar to those from acute exposure. In addition, chronic exposure to wet material may cause effects secondary to tissue destruction.
Ingestion: There are no known or reported effects from chronic ingestion except for effects similar to those experienced from single exposure. The acute corrosivity of this product, makes chronic ingestion of significant amounts unlikely.
Sensitization: This material is not known or reported to be a skin or respiratory sensitizer. -
Carcinogenicity
This product is not known or reported to be carcinogenic by any reference source including IARC, OSHA, NTP or EPA.
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Handling information
Avoid inhalation of dust and fumes. Do not take internally. Avoid contact with skin, eyes and clothing. Upon contact with skin or eyes, wash off with water. Remove contaminated clothing and wash before reuse.
Keep product tightly sealed in original containers. Store product in a cool, dry, well-ventilated area. Store away from combustible or flammable products. Keep product packaging clean and free of all contamination, including, e.g. other pool treatment products, acids, organic materials, nitrogen-containing compounds, dry powder fire extinguishers (containing mono-ammonium phosphate), oxidizers, all corrosive liquids, flammable or combustible materials, etc. -
Disposal information
As a nonhazardous waste, it should be disposed of in accordance with local, state and federal regulations.
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California Prop. 65 Warning
Not listed. -
First Aid
General Advice: Call a poison control center or doctor for treatment advice. For 24-hour emergency medical assistance, call Arch Chemical Emergency Action Network at 1-800-654-6911. Have the product container or label with you when calling a poison control center or doctor, or going for treatment.
Inhalation: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice.
Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice.
Eye Contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
Ingestion: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person.
Notes to Physician: Probable mucosal damage may contraindicate the use of gastric lavage.
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