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CPID

Health effects of consumer products

Valspar Ultra Premium Interior Eggshell Base 2, No. 70728

• Chemical Composition/Ingredients

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

  Back

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers. 

  CAS No./ID

  Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
  EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
  ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
  NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-x

  EC No.

  Percent of chemical in preparation.

  % Conc.

  REACH COMPLIANCE
  EU Hazard Classification Directive 67/548/EEC

  Hazard Symbols are used to classify dangerous substances.

  Hazard Symbols

  Risk Phrases, denoted as a series of numbers preceded by the letter "R" indicate the nature of the special risks, in accordance with Annex III to Directive 67/548/EEC (see Article 23(2)(d) Directive 67/548/EEC). The numbers are separated by either a comma to denote separate statements concerning special risks, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the special risks.

  Risk Phrases

  Safety Phrases, denoted as a series of numbers preceded by the letter "S" indicating the recommended safety precautions, in accordance with Annex IV to Directive 67/548/EEC. The numbers are separated by either a comma to denote separate statements concerning safety precautions, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the safety precautions.

  Safety Phrases

  SVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
  1.  Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
  2.  Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
  3.  Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).

  SVHC?

  --	013463-67-7	--	5.0-10.0		--	--	--
  --	066402-68-4	--	1.0-5.0		--	--	--
  --	014808-60-7	--	1.0-5.0	Xn	--	--	--
  --	007732-18-5	--			--	--	--
  --	000000-02-1	--			--	--	--
  --	001317-95-9	--			--	--	--
  --	025035-69-2	--			--	--	--

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID or EC No. headings to sort values.
  

   

  Sources for Chemical Classifications

  • European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.2
  • European Chemicals Agency, http://echa.europa.eu/
       ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers. 

  CAS No./ID

  Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
  EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
  ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
  NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-x

  EC No.

  Percent of chemical in preparation.

  % Conc.

  California Prop.65 Chemical?

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

   UN Global Harmonization Classification

  Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:

  • Physical Hazard Codes (H200 series)
  • Health Hazard Codes (H300 series)
  • Environmental Hazard Codes (H400 series)
  • Supplementary Hazard Codes (EUH series)

  Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Hazard Statement Code

  Precautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
  Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Precautionary Code

  Pictogram

  SVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
  1.  Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
  2.  Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
  3.  Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).

  SVHC?

  Endocrine Disruptor (ED)

  Titanium dioxide
  013463-67-7 236-675-5	5.0-10.0	No	-- -- -- No No
  Kaolin clay (calcined)
  066402-68-4 266-340-9	1.0-5.0	No	H318 -- No No
  Quartz
  014808-60-7 238-878-4	1.0-5.0	No	-- -- -- No No
  Water
  007732-18-5 231-791-2	--	No	-- -- -- No No
  Trade secret or proprietary formula
  000000-02-1 --	--	No	-- -- -- No No
  Silica (crystalline)
  001317-95-9 --	--	No	-- -- -- No No
  Acrylic Resin
  025035-69-2 --	--	No	-- -- -- No No

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID or EC No. headings to sort values.
  

   

  Sources for Chemical Classifications

  • European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
  • European Chemicals Agency, http://echa.europa.eu/
       ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
• • Hazard Statements

    • • Code
      • Statement
    • H318 : Causes serious eye damage
    • GHS05 : Corrosive
  • Health Effects Information

    • Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.

    • View Material Safety Data Sheet(MSDS)

    • Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product. MSDS DATE :

      September 30, 2008

    • Date when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified. MSDS Verified :

      November 26, 2008

    • 	Health	Flammability	Reactivity
      HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product. HMIS RATING	2*	1	1

    • V.O.C Information

      Volatile Organic Compounds g/L With Solvent : 43

    • SVHC declaration

      This product does not contain any Substances of Very High Concern (SVHC).

    • Warnings

      CAUTIONS:
      CONTAINS CRYSTALLINE SILICA
      May cause eye and skin irritation. Avoid breathing spray mist or dust. If painting indoors, open windows and doors or use other means to ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness, or if air monitoring demonstrates vapor/mist levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH approved) during and after application. Follow respirator manufacturer

    • Acute health effects

      From MSDS
      HAZARDS IDENTIFICATION
      Primary Routes of Exposure: Inhalation; Ingestion; Skin absorption
      Eye Contact: Moderate eye irritation.
      Skin Contact: Causes skin irritation
      Ingestion: Harmful if swallowed.
      Inhalation: Causes respiratory tract irritation. Harmful by inhalation. Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat and cough.
      

    • Chronic health effects

      From MSDS:
      Prolonged exposure to respirable crystalline quartz silica may cause delayed chronic injury (silicosis).

    • Carcinogenicity

      Possible cancer hazard. Contains material which may cause cancer based on animal data. Cancer hazard. Contains material which can cause cancer.
      Contains TIO2 which is listed by IARC as a possible human carcinogen (Group 2B) based on animal data. Neither long term animal studies, nor human epidemiology studies of workers exposed to TIO2 provide an adequate basis to conclude TIO2 is carcinogenic. TIO2 is not classified as a carcinogen by NTP, U.S. OSHA, or the U.S. EPA. Contains crystaline silica. The IARC has determined that crystaline silica inhaled in the form of quartz or cristobablite from occupational sources is carcinogenic to humans (group 1). Refer to IARC monograph 68 in conjunction with the use of these materials. Risk of cancer depends on the duration and level of exposure. In coatings products, risk is due primarily to inhalation of sanding dusts or respirable particles in spray mists. The NTP has also determined that crystaline silica is a known human carcinogen in the form of fine, breathable particles. Risk of cancer depends on duration and level of exposure in coatings products, risk is due primarily to inhalation of sanding dust or respirable particles in spray mist.

    • Handling information

      Keep container closed when not in use. Do not freeze. Since emptied containers may contain product residue, follow all label warnings, even after container is emptied. Do not cut, drill, grind, or weld on or near this container.

    • Disposal information

      Dispose of waste at an approved hazardous waste treatment/disposal facility in accordance with applicable local, provincial and federal regulations.

    • California Prop. 65 Warning

      WARNING: This product contains chemicals known to the State of California to cause cancer.

    • First Aid

      Eye Contact: Get medical attention, if symptoms develop or persist. Immediately flush eye(s) with plenty of water. Remove any contact lenses and open eyes wide apart.
      Skin Contact: Remove contaminated clothing and shoes. Wash off immediately with plenty of water for at least 15 minutes. Get medical attention, if symptoms develop or persist.
      Ingestion: Rinse mouth with water. Give one or two glasses of water. Only induce vomiting at the instruction of medical personnel. Get medical attention immediately.
      Inhalation: Move injured person into fresh air and keep person calm under observation. Get medical attention immediately.
      Medical conditions aggravated by exposure: Any respiratory or skin condition.