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Clairol Mens Choice Haircolor, Natural Dark Brown, M33-08/01/2007-Old Product
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: Men's Hair ColorStructure such as solid, liquid, aerosol etc.
Form: kitDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 14, 2024P.O. Box 599
Cincinnati OH 45201
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
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The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.California Prop.65 Chemical?The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.
UN Global Harmonization Classification
Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Endocrine Disruptor (ED)Hydrogen peroxide
007722-84-1
231-765-01-5 (Developer) No H271, H302, H314, H332, H335, H412 -- 
No No Propylene glycol
000057-55-6
200-338-01-5 (Colorant) No -- -- -- No No Monoethanolamine (MEA)
000141-43-5
205-483-33-7 (Colorant) No H302, H312, H332, H314, H335, H412 P273, P501 No No Hexylene glycol
000107-41-5
203-489-07-13 (Colorant) No H315, H319 -- 
No No Resorcinol
000108-46-3
108-46-30.1-1 (Colorant) No H302, H315, H319, H400 -- 
No No p-Phenylenediamine
000106-50-3
203-404-70.5-5 (Colorant) No H301, H311, H331, H370, H319, H317, H410 P264, P270, P273, P311, P321, P391, P403+P233, P405, P501, P301+P310, P330, P305+P351+P338, P337+P313, P272, P302+P352, P333+P313, P363 
No No Diethylene glycol ethyl ether
000111-90-0
203-919-71-5 (Colorant) No -- -- -- No No Silk Amino Acids
096690-41-4
306-235-8Colorant No -- -- -- No No Wheat protein, hydrolyzed
070084-87-6
--Colorant No -- -- -- No No Ascorbic acid
010504-35-5
--Colorant No -- -- -- No No Tocopherol
000059-02-9
200-412-2Colorant No -- P501 -- No No Tocopheryl acetate
007695-91-2
231-710-0Colorant No -- -- -- No No Water
007732-18-5
231-791-2Developer No -- -- -- No No Acrylates copolymer
000000-45-9
--Developer No -- -- -- No No Oleth-2
005274-65-7
--Developer No -- -- -- No No Oleth-5
005353-27-5
--Developer No -- -- -- No No PEG-50 hydrogenated palmamide
000000-73-6
--Developer No -- -- -- No No Oleth-5
005353-27-5
--Colorant No -- -- -- No No C11-15 pareth-9
068131-40-8
614-295-4Colorant No -- -- -- No No PEG-80 sorbitan laurate
009005-64-5
500-018-3Colorant No -- -- -- No No Oleth-2
005274-65-7
--Colorant No -- -- -- No No Cocamidopropyl betaine
086438-79-1
--Colorant No -- -- -- No No Fragrance(s)/perfume(s)
000000-00-1
--Colorant No -- -- -- No No Dilinoleic acid
006144-28-1
--Colorant No -- -- -- No No Oleic acid
000112-80-1
204-007-1Colorant No -- -- -- No No Isoascorbic acid
000089-65-6
201-928-0Colorant No -- -- -- No No Sodium sulfite
007757-83-7
231-821-4Colorant No -- -- -- No No 1-Naphthol
000090-15-3
201-969-4Colorant No H312, H302, H335, H318 -- No No 3-Aminophenol
000591-27-5
209-711-2Colorant No H411, H400, H317, H302, H332 P264, P270, P301+P312, P330, P261, P271 No No Ethanol, 2,2'-((4-aminophenyl)imino)bis-, sulfate (salt)
058262-44-5
--Colorant No -- -- -- No No Ethylenediaminetetraacetic acid (EDTA)
000060-00-4
200-449-4Colorant No H319 -- No No Panthenol
000081-13-0
201-327-3Colorant No -- -- -- No No 2-Methylresorcinol
000608-25-3
210-155-8Colorant No H301, H317, H318, H400 P273, P391, P501, P264, P270, P301+P310, P321, P330, P405, P280, P305+P351+P338, P310, P261, P272, P302+P352, P333+P313, P362+P364 No No Oleth-10
024871-34-9
--Colorant No -- -- -- No No C12-15 Pareth-3
068131-39-5
500-195-7Colorant No -- -- -- No No Oleamide MIPA
000111-05-7
203-828-2Colorant No H411, H317 -- No No Water
007732-18-5
231-791-2Colorant No -- -- -- No No Soytrimonium chloride
061790-41-8
263-134-0Colorant No H302, H314, H400, H410, EUH071 -- No No Trisodium Ethylenediamine Disuccinate
178949-82-1
416-530-4Colorant No -- -- -- No No Acrylates/Steareth-20 Methacrylate copolymer
000000-50-0
--Developer No -- -- -- No No Oleyl alcohol
000143-28-2
205-597-3Developer No -- -- -- No No Etidronic acid
002809-21-4
220-552-8Developer No H290, H318, H302 P234, P390, P406, P280, P305+P351+P338, P310, P264, P270, P301+P312, P330, P501 No No Disodium EDTA
000139-33-3
205-358-3Developer No -- -- -- No No Simethicone
008050-81-5
--Developer No -- -- -- No No -
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Hazard Statements
-
- Code
- Statement
- H271 : May cause fire or explosion; strong oxidizerH290 : May be corrosive to metalsH301 : Toxic if swallowedH302 : Harmful if swallowedH311 : Toxic in contact with skinH312 : Harmful in contact with skinH314 : Causes severe skin burns and eye damageH315 : Causes skin irritationH317 : May cause an allergic skin reactionH318 : Causes serious eye damageH319 : Causes serious eye irritationH331 : Toxic if inhaledH332 : Harmful if inhaledH335 : May cause respiratory irritationH370 : Causes damage to organsH400 : Very toxic to aquatic lifeH410 : Very toxic to aquatic life with long lasting effectsH411 : Toxic to aquatic life with long lasting effectsH412 : Harmful to aquatic life with long lasting effectsEUH071 : Corrosive to the respiratory tract
- P234 : Keep only in original containerP261 : Avoid breathing dust/fume/gas/mist/vapours/sprayP264 : Wash … thoroughly after handlingP270 : Do not eat, drink or smoke when using this productP271 : Use only outdoors or in a well-ventilated areaP272 : Contaminated work clothing should not be allowed out of the workplaceP273 : Avoid release to the environmentP280 : Wear protective gloves/protective clothing/eye protection/face protectionP310 : Immediately call a POISON CENTER or doctor/physicianP311 : Call a POISON CENTER or doctor/physicianP321 : Specific treatment (see … on this label)P330 : Rinse mouthP363 : Wash contaminated clothing before reuseP390 : Absorb spillage to prevent material-damageP391 : Collect spillageP301+P310 : IF SWALLOWED: Immediately call a POISON CENTER or doctor/physicianP301+P312 : IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwellP302+P352 : IF ON SKIN: Wash with soap and waterP305+P351+P338 : IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to doP333+P313 : If skin irritation or a rash occurs: Get medical advice/attentionP337+P313 : Get medical advice/attentionP405 : Store locked upP406 : Store in a corrosive resistant/… container with a resistant inner linerP501 : Dispose of contents/container to
- GHS03 : OxidiserGHS05 : CorrosiveGHS06 : ToxicGHS07 : IrritantGHS08 : Health HazardGHS09 : Environmentally Hazardous
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Material Safety Data Sheet(MSDS) Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product.
MSDS DATE :August 01, 2007 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATINGN N N -
SVHC declaration
This product does not contain any Substances of Very High Concern (SVHC).
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Warnings
Haircolor products can cause allergic reactions which in rare cases can be Severe. Tattoos may increase your risk of allergy to this product. Conduct a skin allergy test 48 hours before each time you color, even if you have already used coloring products before. So remember to buy the product 48 hours in advance.
Do not use the product at all if:
• you have already experienced any reaction to haircolor products
• you have sensitive, irritated or damaged scalp
In these cases, consult a doctor before dyeing your hair with any haircolor product.
Read and follow instructions on enclosed leaflet. In rare cases, use of hair colorants has been associated with skin depigmentation (skin lightening or loss of color). This may be temporary or permanent. If you notice any skin depigmentation or other allergic reaction such as pain or severe itching, discontinue use immediately.
Caution: This product contains ingredients which may cause skin irritation on certain individuals and a preliminary test according to accompanying directions should first be made. This product must not be used for dyeing the eyelashes or eyebrows; to do so may cause blindness.
Product not intended to be used on children. Keep out of reach of children. -
Acute health effects
From MSDS:
EMERGENCY OVERVIEW:
This is a personal care or cosmetic product that is safe for consumers and other users under intended and reasonably foreseeable use. Additional information on toxicological endpoints is available from the supplier upon request.
POTENTIAL HEALTH EFFECTS:
• Eye: Contact may cause mild to moderate transient irritation. Redness and/or stinging may occur.
• Skin: May cause irritation or sensitization in sensitive individuals. Depending on the nature of any reaction experienced, a similar reaction may occur on subsequent uses of hair color products.
• Inhalation: May cause mild, transient respiratory irritation. Avoid prolonged contact to concentrated vapors.
• Ingestion: Product used as intended is not expected to cause gastrointestinal irritation. Accidental ingestion of undiluted product may cause mild gastrointestinal irritation with nausea, vomiting and diarrhea. -
Chronic health effects
From MSDS:
Finished product is not expected to have chronic health effects.
This product contains ingredients which may cause skin irritation on certain individuals and a preliminary test according to accompanying directions should first be made. This product must not be used for dyeing the eyelashes or eyebrows; to do so may cause blindness.
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Carcinogenicity
Finished product is not expected to be carcinogenic.
NTP: No
IARC: No
OSHA: No -
Handling information
• Precautions for Safe Handling:
For Household Settings: Avoid contact with eyes, skin and clothing. Keep out of the reach of children.
For Non-Household Settings: Avoid contamination with combustible organic matter (e.g., oil, sawdust, damp paper towels, etc.), metal, powder or reducing agents. Contamination may cause decomposition, leading to fire. Decomposition of oxidizing material releases oxygen which may intensify existing fires.
• Conditions for Safe Storage:
For Household Settings: Keep in cool place. Avoid contamination. Keep closed when not in use. Store in the original tightly capped containers away from sunlight, heat, sparks and flame. Do not store any tint, lightener lotion or bleach powder after it has been mixed with developer; the container may rupture. Never return unused material to original container. Empty containers should be rinsed with water before discarding. Keep out of reach of children. Decomposition of hydrogen peroxide may occur with increase in pressure and possible container rupture.
For Non-Household Settings: Store in a well ventilate, cool area. Avoid contamination. Store in the original tightly capped containers away from sunlight, heat, sparks and flame. Decomposition of hydrogen peroxide may occur with increase in pressure and possible container rupture. -
Disposal information
Disposal should be in accordance with Federal, State/Provincial and Local regulations.
For Household Settings:
The following instructions are for consumer usage only. Do not discharge product into natural waters without pre-treatment or adequate dilution.
For Non-Household Settings:
Products covered by this MSDS, in their original form, when disposed as waste, are considered non hazardous waste according to Federal RCRA regulations (40 CFR 261). Disposal should be in accordance with local, state and federal regulations.
California Waste Code: 331 -
California Prop. 65 Warning
This product is not subject to warning labeling under California Proposition 65. -
First Aid
• Eye: Following accidental eye exposure, thorough rinsing of the affected area for 15-20 minutes with clean cold water is recommended. If discomfort or irritation persists, contact a physician. If the eyes or face becomes swollen during or following use, consult a physician or emergency room immediately.
• Skin Problem: Thoroughly rinse with water. Discontinue use of product. If discomfort persists and/or the skin reaction worsens, contact a physician immediately. In cases where discomfort persists and/or medical attention is sought, do not use hair color products again until the specific nature of the skin reaction and the causative agent has been identified by a dermatologist and appropriate medical advice provided.
• Inhalation: If respiratory irritation occurs, remove individual to fresh air.
• Ingestion: Accidental ingestion of product may necessitate medical attention. In case of accidental ingestion dilute with fluids (water or milk) and treat symptomatically. Do not induce vomiting.
Note: After first aid treatment, the caller should be advised that
1) a hospital emergency room or family physician should be consulted if anything unusual occurs or appears necessary in the judgment of the caller, and
2) that the subsequent management of the accident should be dictated by any persistent symptoms and under the direction of the physician.
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