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CPID

Health effects of consumer products

Valspar One & Only Multi Purpose Gloss Enamel, Almond

• Chemical Composition/Ingredients

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

  Advanced
  Primary Chemical Name is the standard name assigned to a chemical substance. Chemical	Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.  CAS No./ID	Percent of chemical in preparation. % Conc.		Chemical of Concern (CoC) Chemical of Concern(CoC)
  Isobutane	000075-28-5	10.0-15.0		Yes  NY-02: EU-CMR Category 1A/1B Annex VI Chemical CA-02: EU-CMR Category 1A/1B Annex VI Chemical MN-01-Minnesota Toxic Free Kids, CHC  CoC List
  Propane	000074-98-6	10.0-15.0		No
  Isopropanol	000067-63-0	1.0-5.0		Yes  CA-20-California OEHHA Non-Cancer End Points Listed Chemicals NY-19: California OEHHA Non-Cancer End Points Listed Chemical  CoC List
  SD Alcohol 38B	000064-17-5	5.0-10.0		Yes  NY-08: IARC Group 1, 2A & 2B Carcinogens NY-23: AOEC Asthmagens CA-09-IARC Group 1, 2A & 2B Carcinogen MN-01-Minnesota Toxic Free Kids, CHC  CoC List
  Ethyl 3-ethoxy propionate	000763-69-9	5.0-10.0		No
  Methyl ethyl ketone	000078-93-3	<5		Yes  NY-09: ATSDR Neurotoxicants NY-17: California Toxic Air Contaminant Chemicals (TACs) CA-10: ATSDR Neurotoxicants CA-18-California Toxic Air Contaminant Chemicals (TACs) MN-01-Minnesota Toxic Free Kids, CHC OR-01: Oregon HPCCCH VT-01: Vermont State CHCC WA-01: Washington State CHCC CA-20-California OEHHA Non-Cancer End Points Listed Chemicals NY-19: California OEHHA Non-Cancer End Points Listed Chemical  CoC List
  Acetone	000067-64-1	35-40		Yes  NY-09: ATSDR Neurotoxicants CA-10: ATSDR Neurotoxicants  CoC List
  Ethylbenzene	000100-41-4	<5		Yes  NY-01: California Prop. 65 Chemical NY-08: IARC Group 1, 2A & 2B Carcinogens NY-09: ATSDR Neurotoxicants NY-16: California Title 22 Chemical Exceeding MCLs NY-17: California Toxic Air Contaminant Chemicals (TACs) NY-18: California Priority Pollulant Chemicals in Water NY-20:CA Environmental Biocontaminant Monitoring Program Priority Chemical NY-24: U.S. EPA TSCA Chemical of Concern CA-01-California Prop. 65 Chemicals CA-09-IARC Group 1, 2A & 2B Carcinogen CA-10: ATSDR Neurotoxicants CA-17-California Title 22 Chemicals Exceeding MCLs CA-18-California Toxic Air Contaminant Chemicals (TACs) CA-19-California Priority Pollulant Chemicals in Water CA-21-California Environmental Biocontaminant Monitoring Program Priority Chemicals MN-01-Minnesota Toxic Free Kids, CHC OR-01: Oregon HPCCCH VT-01: Vermont State CHCC WA-01: Washington State CHCC CA-20-California OEHHA Non-Cancer End Points Listed Chemicals NY-19: California OEHHA Non-Cancer End Points Listed Chemical  CoC List
  Xylene (mixed isomers)	001330-20-7	<10		Yes  NY-04: EPA-IRIS, Neurotoxicity Reference Dose Chemical NY-09: ATSDR Neurotoxicants NY-16: California Title 22 Chemical Exceeding MCLs NY-17: California Toxic Air Contaminant Chemicals (TACs) CA-04: EPA-IRIS, Neurotoxicity Reference Dose Chemical CA-10: ATSDR Neurotoxicants CA-17-California Title 22 Chemicals Exceeding MCLs CA-18-California Toxic Air Contaminant Chemicals (TACs) MN-01-Minnesota Toxic Free Kids, CHC CA-20-California OEHHA Non-Cancer End Points Listed Chemicals NY-19: California OEHHA Non-Cancer End Points Listed Chemical  CoC List
   
  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID headings to sort values.
  

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers. 

  CAS No./ID

  Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
  EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
  ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
  NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-x

  EC No.

  Percent of chemical in preparation.

  % Conc.

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

   UN Global Harmonization Classification

  Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:

  • Physical Hazard Codes (H200 series)
  • Health Hazard Codes (H300 series)
  • Environmental Hazard Codes (H400 series)
  • Supplementary Hazard Codes (EUH series)

  Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Hazard Statement Code

  Precautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
  Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Precautionary Code

  Pictogram

  SVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
  1.  Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
  2.  Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
  3.  Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).

  SVHC?

  Isobutane	000075-28-5	200-857-2	10.0-15.0	H220, H280 P102, P210, P243, P377, P381, P410+P403 No
  Propane	000074-98-6	200-827-9	10.0-15.0	H220, H280 P102, P210, P243, P377, P381, P410+P403 No
  Isopropanol	000067-63-0	200-661-7	1.0-5.0	H225, H319, H336 P102, P210, P233, P241, P242, P243, P261, P264, P271, P280, P405, P501, P303+P361+P353, P370+P378, P337+P313, P305+P351+P338, P304+P340, P312, P403+P233, P403+P235 No
  SD Alcohol 38B	000064-17-5	200-578-6	5.0-10.0	H225, H319 P210, P233, P240, P241, P242, P243, P264, P280, P303+P361+P353, P370+P378, P305+P351+P338, P337+P313, P403+P235, P501 No
  Ethyl 3-ethoxy propionate	000763-69-9	212-112-9	5.0-10.0	H226, EUH066 P332+P313, P210, P370+P378, P403+P235, P501 No
  Methyl ethyl ketone	000078-93-3	201-159-0	<5	H225, H319, H336, EUH066 P102, P210, P233, P240, P241, P242, P243, P261, P264, P271, P280, P405, P501, P303+P361+P353, P304+P340, P305+P351+P338, P312, P337+P313, P370+P378, P403+P233, P403+P235 No
  Acetone	000067-64-1	200-662-2	35-40	H225, H319, H336, EUH066 P210, P233, P240, P241, P242, P243, P261, P264, P271, P280, P304+P340, P305+P351+P328, P312, P337+P313, P403+P233, P405, P501 No
  Ethylbenzene	000100-41-4	202-849-4	<5	H225, H332 P201, P202, P210, P233, P240, P241, P242, P243, P260, P261, P271, P280, P281, P303+P361+P353, P304+P340, P308+P313, P312, P314, P370+P378, P403+P235, P405, P501 No
  Xylene (mixed isomers)	001330-20-7	215-535-7	<10	H226, H312, H332, H315 P210, P243, P260, P280, P303+P361+P353, P332+P313 No

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID or EC No. headings to sort values.
  

   

  Sources for Chemical Classifications

  • European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
  • European Chemicals Agency, http://echa.europa.eu/
       ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
• • Health Effects Information

    • Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.

    • Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product. MSDS DATE :

      October 02, 2000

    • 	Health	Flammability	Reactivity
      HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product. HMIS RATING	N	N	N

    • Warnings

      Extremely flammable liquid and vapor. Vapors may cause flash fires. Contents under pressure. Vapor harmful. May affect the brain or nervous system causing dizziness, headache, or nausea. Causes eye, nose, throat and skin irritation. Do not puncture or incinerate container. Exposure to heat or prolonged exposure to sun may cause bursting. Do not expose to heat or store at temperatures above 120 degrees F. Contains propane as pressurizing agent. Vapors may ignite explosively. Keep away from heat sparks and flame. Do not smoke. Extinguish all flames and pilot lights and turn off stoves, heaters, electric motors and other sources of ignition during use and until all vapors are gone. Prevent buildup of vapors by opening all windows and doors to achieve cross ventilation. Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. To avoid breathing vapors or spray mist, open windows and doors or use other means to ensure fresh air entry during application and drying. If you experience eye watering, headaches or dizziness, increase respiratory protection. (NIOSH/MSHA approved) or leave the area. Close container after each use. Avoid contact with eyes, skin and clothing. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Keep out of reach of children.

    • Acute health effects

      From MSDS EFFECTS OF OVEREXPOSURE: Inhalation: Harmful if inhaled. May affect the brain, nervous system or respiratory system, causing dizziness, headache, nausea or respiratory irritation. Overexposure to ingredients in this product may cause nose and throat irritation, liver damage, kidney damage, respiratory tract irritation, skin sensitization, mucous membrane irritation. Eye Contact: May cause eye irritation. Skin Contact: May cause skin irritation. Ingestion: Not listed. Medical Conditions Generally Aggravated by Exposure: Any respiratory or skin condition.

    • Chronic health effects

      From MSDS Contains ingredients which may cause skin sensitization. Possible birth defects hazard. Contains ingredients which may cause birth defects based on animal data. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling this product may be harmful or fatal.

    • Carcinogenicity

      From MSDS Contains ethylbenzene, which has been determined by NTP to be an animal carcinogen with no known relevance to humans. IARC has classified ethylbenzene as possibly carcinogenic to humans (Group 2B) on the basis of sufficient evidence of carcinogenicity in laboratory animals but inadequate evidence for cancer in humans.

    • Handling information

      From MSDS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Containers should be grounded/bonded when pouring. Avoid free fall of liquid in excess of a few inches. Keep away from heat, sparks and open flames. Deep container closed when not in use. Do not store above 120oF (49oC). Based on the product flash point and vapor pressure, suitable storage should be provided in accordance with OSHA regulation 1910.106. Empty containers may contain product residue, including flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must be observed until the container has been cleaned or reconditioned.

    • Disposal information

      From MSDS Dispose in chemical disposal area or in a manner that complies with federal, state, and local regulations. Do not incinerate closed containers.

    • First Aid

      From MSDS EYE CONTACT: Flush immediately with plenty of water for at least 15 minutes and get medical attention. SKIN CONTACT: Wash thoroughly with soap and water. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean contaminated shoes. INHALATION: If affected by inhalation of vapor or spray mist, remove to fresh air. SWALLOWING: If swallowed, contact medical personnel immediately to determine best course of action.