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CPID

Health effects of consumer products

Valspar One & Only Multi Purpose Gray Metal Primer

• Chemical Composition/Ingredients

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

  Back

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers. 

  CAS No./ID

  Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
  EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
  ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
  NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-x

  EC No.

  Percent of chemical in preparation.

  % Conc.

  REACH COMPLIANCE
  EU Hazard Classification Directive 67/548/EEC

  Hazard Symbols are used to classify dangerous substances.

  Hazard Symbols

  Risk Phrases, denoted as a series of numbers preceded by the letter "R" indicate the nature of the special risks, in accordance with Annex III to Directive 67/548/EEC (see Article 23(2)(d) Directive 67/548/EEC). The numbers are separated by either a comma to denote separate statements concerning special risks, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the special risks.

  Risk Phrases

  Safety Phrases, denoted as a series of numbers preceded by the letter "S" indicating the recommended safety precautions, in accordance with Annex IV to Directive 67/548/EEC. The numbers are separated by either a comma to denote separate statements concerning safety precautions, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the safety precautions.

  Safety Phrases

  SVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
  1.  Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
  2.  Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
  3.  Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).

  SVHC?

  --	000075-28-5	--	10.0-15.0	F+	--	--	--
  --	000074-98-6	--	10.0-15.0	F+	--	--	--
  --	000067-63-0	--	1.0-5.0	F, Xi	--	--	--
  --	000064-17-5	--	5.0-10.0		--	--	--
  --	000763-69-9	--	5.0-10.0		--	--	--
  --	000078-93-3	--	<5	Xi, F	--	--	--
  --	000067-64-1	--	35-40	F, Xi	--	--	--
  --	000100-41-4	--	<5	F, Xn	--	--	--
  --	001330-20-7	--	<10		--	--	--

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID or EC No. headings to sort values.
  

   

  Sources for Chemical Classifications

  • European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.2
  • European Chemicals Agency, http://echa.europa.eu/
       ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers. 

  CAS No./ID

  Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
  EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
  ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
  NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-x

  EC No.

  Percent of chemical in preparation.

  % Conc.

  California Prop.65 Chemical?

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

   UN Global Harmonization Classification

  Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:

  • Physical Hazard Codes (H200 series)
  • Health Hazard Codes (H300 series)
  • Environmental Hazard Codes (H400 series)
  • Supplementary Hazard Codes (EUH series)

  Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Hazard Statement Code

  Precautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
  Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Precautionary Code

  Pictogram

  SVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
  1.  Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
  2.  Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
  3.  Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).

  SVHC?

  Endocrine Disruptor (ED)

  Isobutane
  000075-28-5 200-857-2	10.0-15.0	No	H220, H280 P102, P210, P243, P377, P381, P410+P403 No No
  Propane
  000074-98-6 200-827-9	10.0-15.0	No	H220, H280 P102, P210, P243, P377, P381, P410+P403 No No
  Isopropanol
  000067-63-0 200-661-7	1.0-5.0	No	H225, H319, H336 P102, P210, P233, P241, P242, P243, P261, P264, P271, P280, P405, P501, P303+P361+P353, P370+P378, P337+P313, P305+P351+P338, P304+P340, P312, P403+P233, P403+P235 No No
  SD Alcohol 38B
  000064-17-5 200-578-6	5.0-10.0	No	H225, H319 P210, P233, P240, P241, P242, P243, P264, P280, P303+P361+P353, P370+P378, P305+P351+P338, P337+P313, P403+P235, P501 No No
  Ethyl 3-ethoxy propionate
  000763-69-9 212-112-9	5.0-10.0	No	H226, EUH066 P332+P313, P210, P370+P378, P403+P235, P501 No No
  Methyl ethyl ketone
  000078-93-3 201-159-0	<5	No	H225, H319, H336, EUH066 P102, P210, P233, P240, P241, P242, P243, P261, P264, P271, P280, P405, P501, P303+P361+P353, P304+P340, P305+P351+P338, P312, P337+P313, P370+P378, P403+P233, P403+P235 No No
  Acetone
  000067-64-1 200-662-2	35-40	No	H225, H319, H336, EUH066 P210, P233, P240, P241, P242, P243, P261, P264, P271, P280, P304+P340, P305+P351+P328, P312, P337+P313, P403+P233, P405, P501 No No
  Ethylbenzene
  000100-41-4 202-849-4	<5	Yes	H225, H332 P201, P202, P210, P233, P240, P241, P242, P243, P260, P261, P271, P280, P281, P303+P361+P353, P304+P340, P308+P313, P312, P314, P370+P378, P403+P235, P405, P501 No No
  Xylene (mixed isomers)
  001330-20-7 215-535-7	<10	No	H226, H312, H332, H315 P210, P243, P260, P280, P303+P361+P353, P332+P313 No No

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID or EC No. headings to sort values.
  

   

  Sources for Chemical Classifications

  • European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
  • European Chemicals Agency, http://echa.europa.eu/
       ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
• • Hazard Statements

    • • Code
      • Statement
    • H220 : Extremely flammable gas
      H225 : Highly flammable liquid and vapour
      H226 : Flammable liquid and vapour
      H280 : Contains gas under pressure; may explode if heated
      H312 : Harmful in contact with skin
      H315 : Causes skin irritation
      H319 : Causes serious eye irritation
      H332 : Harmful if inhaled
      H336 : May cause drowsiness or dizziness.
      EUH066 : Repeated exposure may cause skin dryness or cracking
    • P102 : Keep out of reach of children
      P201 : Obtain special instructions before use
      P202 : Do not handle until all safety precautions have been read and understood
      P210 : Keep away from heat/sparks/open flames/hot surfaces
      P233 : Keep container tightly closed
      P240 : Ground/bond container and receiving equipment
      P241 : Use explosion-proof electrical/ventilating/light/…/equipment
      P242 : Use only non-sparking tools
      P243 : Take precautionary measures against static discharge
      P260 : Do not breathe dust/fume/gas/mist/vapours/spray
      P261 : Avoid breathing dust/fume/gas/mist/vapours/spray
      P264 : Wash … thoroughly after handling
      P271 : Use only outdoors or in a well-ventilated area
      P280 : Wear protective gloves/protective clothing/eye protection/face protection
      P281 : Use personal protective equipment as required
      P312 : Call a POISON CENTER or doctor/physician if you feel unwell
      P314 : Get Medical advice/attention if you feel unwell
      P377 : Leaking gas fire
      P381 : Eliminate all ignition sources if safe to do so
      P303+P361+P353 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
      P304+P340 : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
      P305+P351+P338 : IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do
      P308+P313 : If exposed or concerned: Get medical advice/attention
      P332+P313 : If skin irritation occurs: Get medical advice/attention
      P337+P313 : Get medical advice/attention
      P370+P378 : In case of fire: Use … for extinction
      P405 : Store locked up
      P501 : Dispose of contents/container to
    • GHS02 : Flammable
      GHS04 : Compressed Gas
      GHS07 : Irritant
  • Health Effects Information

    • Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.

    • Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product. MSDS DATE :

      October 02, 2000

    • 	Health	Flammability	Reactivity
      HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product. HMIS RATING	N	N	N

    • SVHC declaration

      This product does not contain any Substances of Very High Concern (SVHC).

    • Warnings

      Extremely flammable liquid and vapor. Vapors may cause flash fires. Contents under pressure. Vapor harmful. May affect the brain or nervous system causing dizziness, headache, or nausea. Causes eye, nose, throat and skin irritation. Do not puncture or incinerate container. Exposure to heat or prolonged exposure to sun may cause bursting. Do not expose to heat or store at temperatures above 120 degrees F. Contains propane as pressurizing agent. Vapors may ignite explosively. Keep away from heat sparks and flame. Do not smoke. Extinguish all flames and pilot lights and turn off stoves, heaters, electric motors and other sources of ignition during use and until all vapors are gone. Prevent buildup of vapors by opening all windows and doors to achieve cross ventilation. Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. To avoid breathing vapors or spray mist, open windows and doors or use other means to ensure fresh air entry during application and drying. If you experience eye watering, headaches or dizziness, increase respiratory protection. (NIOSH/MSHA approved) or leave the area. Close container after each use. Avoid contact with eyes, skin and clothing. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Keep out of reach of children.

    • Acute health effects

      From MSDS EFFECTS OF OVEREXPOSURE: Inhalation: Harmful if inhaled. May affect the brain, nervous system or respiratory system, causing dizziness, headache, nausea or respiratory irritation. Overexposure to ingredients in this product may cause nose and throat irritation, liver damage, kidney damage, CNS Depression, respiratory tract irritation, mucous membrane irritation. Eye Contact: May cause eye irritation. Skin Contact: May cause skin irritation. Ingestion: Not listed. Medical Conditions Generally Aggravated by Exposure: Any respiratory or skin condition.

    • Chronic health effects

      From MSDS Possible birth defects hazard. Contains ingredients which may cause birth defects based on animal data. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling this product may be harmful or fatal. Contains ingredients which may cause liver damage, kidney damage.

    • Carcinogenicity

      From MSDS Contains ethylbenzene, which has been determined by NTP to be an animal carcinogen with no known relevance to humans. IARC has classified ethylbenzene as possibly carcinogenic to humans (Group 2B) on the basis of sufficient evidence of carcinogenicity in laboratory animals but inadequate evidence for cancer in humans.

    • Handling information

      From MSDS Keep away from heat, sparks and open flames. Deep container closed when not in use. Do not store above 120F. Based on the product flash point and vapor pressure suitable storage should be provided in accordance with OSHA regulation 1910.106. Empty containers may contain product residue, including flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must be observed until the container has been cleaned or reconditioned.

    • Disposal information

      From MSDS Dispose in chemical disposal area or in a manner that complies with federal, state, and local regulations. Do not incinerate closed containers.

    • First Aid

      From MSDS EYE CONTACT: Flush immediately with plenty of water for at least 15 minutes and get medical attention. SKIN CONTACT: Wash thoroughly with soap and water. INHALATION: If affected by inhalation of vapor or spray mist, remove to fresh air. SWALLOWING: If swallowed, do not induce vomiting. Give large quantities of water. If available, give several glasses of milk. Never give anything by mouth to an unconscious person. Get medical attention immediately.