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CPID

Health effects of consumer products

Ortho Isotox Insect Killer Formula IV-Old Product

• Chemical Composition/Ingredients

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

  Advanced
  Primary Chemical Name is the standard name assigned to a chemical substance. Chemical	Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.  CAS No./ID	Percent of chemical in preparation. % Conc.		Chemical of Concern (CoC) Chemical of Concern(CoC)
  Acephate	030560-19-1	8		Yes  NY-04: EPA-IRIS, Neurotoxicity Reference Dose Chemical NY-20:CA Environmental Biocontaminant Monitoring Program Priority Chemical CA-04: EPA-IRIS, Neurotoxicity Reference Dose Chemical CA-21-California Environmental Biocontaminant Monitoring Program Priority Chemicals  CoC List
  Hexakis(2-methyl-2-phenypropyl)distannoxane	013356-08-6	0.5		Yes  MN-01-Minnesota Toxic Free Kids, CHC  CoC List
  Inert ingredients (unspecified)	999999-00-2	91.5		No
  Isopropanol	000067-63-0	--		Yes  CA-20-California OEHHA Non-Cancer End Points Listed Chemicals NY-19: California OEHHA Non-Cancer End Points Listed Chemical  CoC List
  N-Methylpyrrolidone	000872-50-4	--		Yes  NY-01: California Prop. 65 Chemical NY-24: U.S. EPA TSCA Chemical of Concern CA-01-California Prop. 65 Chemicals MN-01-Minnesota Toxic Free Kids, CHC OR-01: Oregon HPCCCH VT-01: Vermont State CHCC WA-01: Washington State CHCC  CoC List
  Toximul 3406F	000000-18-2	--		No
   
  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID headings to sort values.
  

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers. 

  CAS No./ID

  Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
  EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
  ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
  NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-x

  EC No.

  Percent of chemical in preparation.

  % Conc.

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

   UN Global Harmonization Classification

  Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:

  • Physical Hazard Codes (H200 series)
  • Health Hazard Codes (H300 series)
  • Environmental Hazard Codes (H400 series)
  • Supplementary Hazard Codes (EUH series)

  Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Hazard Statement Code

  Precautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
  Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Precautionary Code

  Pictogram

  SVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
  1.  Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
  2.  Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
  3.  Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).

  SVHC?

  Acephate	030560-19-1	250-241-2	8	H302 ------- No
  Hexakis(2-methyl-2-phenypropyl)distannoxane	013356-08-6	236-407-7	0.5	H330 H319 H315 H410 ------- No
  Inert ingredients (unspecified)	999999-00-2	--	91.5	-------- ------- ---- No
  Isopropanol	000067-63-0	200-661-7	--	H225, H319, H336 P102, P210, P233, P241, P242, P243, P261, P264, P271, P280, P405, P501, P303+P361+P353, P370+P378, P337+P313, P305+P351+P338, P304+P340, P312, P403+P233, P403+P235 No
  N-Methylpyrrolidone	000872-50-4	212-828-1	--	H360, H319, H335, H315 ------- Yes
  Toximul 3406F	000000-18-2	--	--	-------- ------- ---- No

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID or EC No. headings to sort values.
  

   

  Sources for Chemical Classifications

  • European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
  • European Chemicals Agency, http://echa.europa.eu/
       ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
• • Health Effects Information

    • Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.

    • Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product. MSDS DATE :

      February 14, 1997

    • 	Health	Flammability	Reactivity
      HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product. HMIS RATING	3	3	0

    • Warnings

      CAUSES IRREVERSIBLE EYE DAMAGE - CAUSES SKIN IRRITATION - MAY BE HARMFUL IF SWALLOWED OR ABSORBED THROUGH THE SKIN - DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING - FLAMMABLE - KEEP OUT OF REACH OF CHILDREN

    • Acute health effects

      From MSDS POTENTIAL HEALTH EFFECTS EYES: This substance is a severe eye irritant and could cause permanent damage to your eyes and blindness. The degree of the injury will depend on the amount of material that gets into the eye and the speed and thoroughness of the first aid treatment. Symptoms of overexposure may include discomfort, irritation and redness, and blurred vision. SKIN: The undiluted product is considered a moderate skin irritant, therefore contact with the skin can cause prolonged (days) injury to the affected area. The degree of injury will depend on the amount of material that gets on the skin and the speed and thoroughness of the first aid treatment. Skin irritation may include redness, itching and swelling. This substance is considered slightly toxic to internal organs if absorbed through the skin. INGESTION: This substance is slightly toxic to internal organs if swallowed. This product contains a petroleum distillate. Because of the low viscosity of the petroleum distillate, it can directly enter or be aspirated into the lungs either during swallowing or vomiting the substance. Once in the lungs, the substance is very difficult to remove and can cause severe injury to the lungs and death. INHALATION: If inhaled, this substance is considered practically non-toxic to internal organs. TARGET ORGANS: Acephate is an inhibitor of the cholinesterase enzyme, found in nervous tissue, red blood cells, and plasma.

    • Chronic health effects

      From MSDS SUB This product contains acephate, an organophosphate that is considered to be a cholinesterase inhibitor. Cholinesterase is an enzyme involved in the transmission of nerve impulses. Therefore, repeated daily exposure to the product can gradually lower the cholinesterase levels to a point that signs and symptoms of organophosphate poisoning may occur. Results of the rat chronic acephate feeding study indicate that the no observed effect level (NOEL) was 5 parts per million (ppm) or (0.25 mg/kg/dy). Hexakis NOEL's for the rat chronic and 2-year dog studies are 2,000 and 16,000 ppm (100 and 400 mg/kg/dy), respectively. The dog 2-year acephate feeding study NOEL for cholinesterase inhibition was 30 ppm (0.75 mg/kg/dy). The effect level for cholinesterase inhibition occurred at the high dose of 200 ppm (5 mg/kg/dy). NEUROTOXICITY: Based on the results of the chicken neurotoxicity studies, acephate has not demonstrated potential to cause delayed neuropathy. Hexakis has not been associated with neuro-histopathological changes. TERATOGENICITY: Neither acephate, or hexakis have been demonstrated to cause birth defects. REPRODUCTIVE TOXIN: When male and female rats were fed acephate continuously for two generations through weaning of the third generation, animals in the mid and high-dose groups demonstrated compound-related effects on reproductive performance. The low-dose was considered the no-effect-level. There was no evidence of adverse reproductive effects in the hexakis rat 3 generation study. MUTAGENICITY: Acephate has demonstrated weak mutagenic potential in microbes or cultured cells, while results of in vivo studies indicate that it does not cause mutation in whole animals. Hexakis is not considered to be a mutagen in either in vitro or in vivo studies.

    • Carcinogenicity

      From MSDS CARCINOGENICITY COMMENTS: EPA has classed acephate in category C as a possible human carcinogen based on the liver tumor findings in the mouse lifetime feeding study. Liver pathology was observed at dose levels of 250 and 1000 ppm (37.5 and 150 mg/kg/dy), while an increased incidence of liver cancer was noted in the high dose (150 mg/kg/dy) female mice only. Acephate has not demonstrated any evidence of carcinogenic potential in any other species. Hexakis was not carcinogenic in either the rat or mouse lifetime feeding studies or the 2 year dog chronic study.

    • Handling information

      From MSDS GENERAL PROCEDURES: Store away from heat or open flame. Keep pesticide in original container. Do not put concentrate or dilute into food or drink containers. Avoid contamination of feed, foodstuffs. Store in a cool dry place, preferably in a locked storage area. Do not store diluted spray. Store above freezing. Handle concentrate in a ventilated area. Keep container closed. ECOTOXICOLOGICAL INFORMATION: This material is toxic to fish and birds. Drift and runoff from treated areas may be hazardous to aquatic organisms in neighboring areas. Do not apply directly to water. Do not contaminate water by cleaning of equipment or disposal of wastes. Do not apply this product or allow it to drift to blooming crops or weeds if bees are visiting treatment area.

    • Disposal information

      From MSDS If necessary to dispose of partially filled product container, securely wrap it in several layers of newspaper and discard in trash. EMPTY CONTAINER: Do not reuse container. Rinse thoroughly before discarding in trash.

    • First Aid

      From MSDS EYES: Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eyes. Call a poison control center or doctor for treatment advice. SKIN: If on skin or clothing, take off contaminated clothing. Rinse skin immediately with plenty of water for 15 to 20 minutes. Call a poison control center or doctor for treatment advice. INGESTION: If swallowed, call a poison control center or doctor immediately for treatment advice. Have person sip glass of water if able to swallow. Do not induce vomiting unless told to by a poison control center or doctor. Never give anything by mouth to an unconscious person. INHALATION: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by mouth-to-mouth, if possible. Call a poison control center or doctor for further treatment advice. NOTES TO PHYSICIAN: Ingestion of this product or subsequent vomiting can result in aspiration of light hydrocarbon liquid which can cause pneumonitis. This material contains a cholinesterase inhibitor. Measurement of blood cholinesterase activity may be useful in monitoring exposure. If signs of cholinesterase inhibition appear, atropine sulfate is antidotal. 2-PAM (PROTOPAM) is also antidotal and may be used in conjunction with atropine but should not be used alone.