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CPID

Health effects of consumer products

Quikrete Polyurethane Sealant, Self-Leveling No. 8660-10, 8660-30-Old Product

• Chemical Composition/Ingredients

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

  Advanced
  Primary Chemical Name is the standard name assigned to a chemical substance. Chemical	Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.  CAS No./ID	Percent of chemical in preparation. % Conc.		Chemical of Concern (CoC) Chemical of Concern(CoC)
  Calcium carbonate (Limestone)	001317-65-3	15.0-40.0		No
  Butyl benzyl phthalate	000085-68-7	10.0-30.0		Yes  NY-01: California Prop. 65 Chemical NY-03: EU-SVHC-Endocrine Disruptor Chemical NY-11: NTP Reproductive or Developmental Toxicant NY-18: California Priority Pollulant Chemicals in Water NY-20:CA Environmental Biocontaminant Monitoring Program Priority Chemical NY-24: U.S. EPA TSCA Chemical of Concern NY-29: Short List Of Chemicals of Concern CA-01-California Prop. 65 Chemicals CA-03: EU-SVHC-Endocrine Disruptor Chemical CA-8-EU-Respiratory Sensitizors Annex VI Chemical CA-12-NTP Reproductive or Developmental Toxicants CA-19-California Priority Pollulant Chemicals in Water CA-21-California Environmental Biocontaminant Monitoring Program Priority Chemicals CA-23-Nonfunctional Constituents ME-02-Maine Childrens Products Priority Chemicals MN-01-Minnesota Toxic Free Kids, CHC MN-02-Minnesota Toxic Free Kids, Priority Chemicals OR-01: Oregon HPCCCH VT-01: Vermont State CHCC WA-01: Washington State CHCC  CoC List
  Titanium dioxide	013463-67-7	1.0-5.0		Yes  NY-08: IARC Group 1, 2A & 2B Carcinogens CA-09-IARC Group 1, 2A & 2B Carcinogen MN-01-Minnesota Toxic Free Kids, CHC  CoC List
  Xylene (mixed isomers)	001330-20-7	1.0-5.0		Yes  NY-04: EPA-IRIS, Neurotoxicity Reference Dose Chemical NY-09: ATSDR Neurotoxicants NY-16: California Title 22 Chemical Exceeding MCLs NY-17: California Toxic Air Contaminant Chemicals (TACs) CA-04: EPA-IRIS, Neurotoxicity Reference Dose Chemical CA-10: ATSDR Neurotoxicants CA-17-California Title 22 Chemicals Exceeding MCLs CA-18-California Toxic Air Contaminant Chemicals (TACs) MN-01-Minnesota Toxic Free Kids, CHC CA-20-California OEHHA Non-Cancer End Points Listed Chemicals NY-19: California OEHHA Non-Cancer End Points Listed Chemical  CoC List
  Calcium oxide	001305-78-8	1.0-5.0		No
  Methylene bisphenyl diisocyanate (MDI)	000101-68-8	0.5-1.5		Yes  NY-04: EPA-IRIS, Neurotoxicity Reference Dose Chemical NY-17: California Toxic Air Contaminant Chemicals (TACs) NY-23: AOEC Asthmagens CA-04: EPA-IRIS, Neurotoxicity Reference Dose Chemical CA-8-EU-Respiratory Sensitizors Annex VI Chemical CA-18-California Toxic Air Contaminant Chemicals (TACs) MN-01-Minnesota Toxic Free Kids, CHC CA-20-California OEHHA Non-Cancer End Points Listed Chemicals NY-19: California OEHHA Non-Cancer End Points Listed Chemical  CoC List
  Ethylbenzene	000100-41-4	0.1-1		Yes  NY-01: California Prop. 65 Chemical NY-08: IARC Group 1, 2A & 2B Carcinogens NY-09: ATSDR Neurotoxicants NY-16: California Title 22 Chemical Exceeding MCLs NY-17: California Toxic Air Contaminant Chemicals (TACs) NY-18: California Priority Pollulant Chemicals in Water NY-20:CA Environmental Biocontaminant Monitoring Program Priority Chemical NY-24: U.S. EPA TSCA Chemical of Concern CA-01-California Prop. 65 Chemicals CA-09-IARC Group 1, 2A & 2B Carcinogen CA-10: ATSDR Neurotoxicants CA-17-California Title 22 Chemicals Exceeding MCLs CA-18-California Toxic Air Contaminant Chemicals (TACs) CA-19-California Priority Pollulant Chemicals in Water CA-21-California Environmental Biocontaminant Monitoring Program Priority Chemicals MN-01-Minnesota Toxic Free Kids, CHC OR-01: Oregon HPCCCH VT-01: Vermont State CHCC WA-01: Washington State CHCC CA-20-California OEHHA Non-Cancer End Points Listed Chemicals NY-19: California OEHHA Non-Cancer End Points Listed Chemical  CoC List
   
  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID headings to sort values.
  

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers. 

  CAS No./ID

  Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
  EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
  ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
  NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-x

  EC No.

  Percent of chemical in preparation.

  % Conc.

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

   UN Global Harmonization Classification

  Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:

  • Physical Hazard Codes (H200 series)
  • Health Hazard Codes (H300 series)
  • Environmental Hazard Codes (H400 series)
  • Supplementary Hazard Codes (EUH series)

  Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Hazard Statement Code

  Precautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
  Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Precautionary Code

  Pictogram

  SVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
  1.  Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
  2.  Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
  3.  Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).

  SVHC?

  Calcium carbonate (Limestone)	001317-65-3	215-279-6	15.0-40.0	-------- ------- ---- No
  Butyl benzyl phthalate	000085-68-7	201-622-7	10.0-30.0	H400, H360, H410 P501, P405, P391, P308+P313, P281, P273, P201, P202   Yes
  Titanium dioxide	013463-67-7	236-675-5	1.0-5.0	-------- ------- ---- No
  Xylene (mixed isomers)	001330-20-7	215-535-7	1.0-5.0	H226, H312, H332, H315 P210, P243, P260, P280, P303+P361+P353, P332+P313 No
  Calcium oxide	001305-78-8	215-138-9	1.0-5.0	H315, H318, H335 P102, P280, P305, P351:, P310, P302+P352, P261, P304+P340, P501 No
  Methylene bisphenyl diisocyanate (MDI)	000101-68-8	202-966-0	0.5-1.5	H332, H315, H319, H334, H317, H351, H335, H373, EUH204 P260, P280, P284, P302+P352, P304+P340, P305+P351+P338, P308+P313 No
  Ethylbenzene	000100-41-4	202-849-4	0.1-1	H225, H332 P201, P202, P210, P233, P240, P241, P242, P243, P260, P261, P271, P280, P281, P303+P361+P353, P304+P340, P308+P313, P312, P314, P370+P378, P403+P235, P405, P501 No

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID or EC No. headings to sort values.
  

   

  Sources for Chemical Classifications

  • European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
  • European Chemicals Agency, http://echa.europa.eu/
       ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
• • Health Effects Information

    • Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.

    • MSDS DATE :

      February 01, 2004

    • 	Health	Flammability	Reactivity
      HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product. HMIS RATING	2	2	0

    • Acute health effects

      From MSDS MOST IMPORTANT HAZARDS MAIN SYMPTOMS: EYE: Direct contact irritates moderately with redness and swelling. Calcium carbonate, xylene, calcium oxide, and MDI may cause severe eye irritation, especially in dust form. Butyl benzyl phthalate (BBP) may cause irritation with symptoms of redness and itching. SKIN: A single short exposure (less than 24 hours) may irritate. Repeated prolonged contact (24 to 48 hours) may irritate moderately. Product contains calcium carbonate, xylene, and calcium oxide, which are possible skin sensitizers. Contact with BBP may cause irritation with symptoms of redness and itching. MDI may cause irritation to the skin or mucous membranes. Ethyl benzene may be absorbed through the skin. INHALATION: Vapor overexposure may severely irritate eyes, nose, throat, upper respiratory tract, and lungs. Vapor overexposure may cause drowsiness. Excessive inhalation of calcium carbonate (dust form) may result in shortness of breath or reduced pulmonary function. Inhalation of high concentrations of BBP, xylene, or ethyl benzene may cause respiratory irritation or difficulties and central nervous system effects characterized by headache, nausea, dizziness, and/or drowsiness. MDI vapors or mist can cause irritation of upper respiratory tract: signs/symptoms can include soreness of the nose and throat, coughing, and sneezing. Persons previously sensitized to isocyanates may experience an allergic respiratory reaction: signs/symptoms can include difficulty breathing, wheezing, tightness of chest, and respiratory failure. Overexposure to titanium dioxide (dust form) may cause pulmonary fibrosis (scarring of the lungs). ORAL: Small amounts transferred to the mouth by fingers during use, etc. should not injure. Swallowing large amounts may cause digestive discomfort and gastrointestinal irritation. Ingestion of BBP may cause central nervous system depression with symptoms seen in acute inhalation. Ingestion of xylene may cause central nervous system effects. Aspiration of xylene or ethyl benzene into lungs may cause chemical pneumonitis.

    • Chronic health effects

      From MSDS SKIN: Repeat contact with skin may cause severe irritation, sensitization, or allergic reaction. Prolonged skin contact with xylene or ethyl benzene may cause skin irritation or dermatitis. Chronic exposure to calcium oxide may cause severe corrosive damage. INHALATION: Vapor overexposure may cause drowsiness, irritate eyes, nose, and throat, or injure blood, liver, or central nervous system. Prolonged inhalation of dust (including calcium carbonate and titanium dioxide in dust form) may cause respiratory effects including shortness of breath, reduced pulmonary function, and pulmonary fibrosis (scarring of the lungs). Chronic exposure to BBP by inhalation may cause sleepiness, withdrawal and weight loss or decreased weight gain. Chronic exposure to xylene may cause damage to the eyes, central nervous system, bone marrow, liver, or kidneys. Chronic inhalation of calcium oxide may cause inflammation and ulcers in the respiratory system. Chronic overexposure to isocyanates (found in MDI) may cause lung damage and isocyanate sensitization (chemical asthma), which may be temporary or permanent. Chronic inhalation of ethyl benzene may have central nervous effects. ORAL: Small amounts transferred to the mouth by fingers during use, etc. should not injure. Swallowing larger quantities may have adverse effects depending on quantity ingested. Repeated ingestion of BBP may cause sleepiness, withdrawal, and weight loss or decreased weight gain. Ingestion of xylene may cause central nervous system effects.

    • Carcinogenicity

      From MSDS CARCINOGENICITY: BUTYL BENZYL PHTHALATE: The IARC has evaluated this chemical and listed it as Group 3, not classifiable as to its carcinogenicity to humans. TITANIUM DIOXIDE: The IARC has evaluated this chemical and listed it as Group 3, not classifiable as to its carcinogenicity to humans. XYLENE: The IARC has evaluated this chemical and listed it as Group 3, not classifiable as to its carcinogenicity to humans. MDI: The IARC has evaluated this chemical and listed it as Group 3, not classifiable as to its carcinogenicity to humans. ETHYL BENZENE: The IARC has evaluated this chemical and listed it as Group 2B, possibly carcinogenic to humans.

    • Handling information

      From MSDS Assure good ventilation. Eliminate sources of ignition, store in original sealed containers away from heat and moisture. Avoid eye contact. Use proper protection - safety glasses as a minimum. Avoid skin contact. Protect hands with impervious rubber gloves and wear typical full cover clothing. Gloves must be checked before each use for signs of degradation

    • Disposal information

      From MSDS When a decision is made to discard this material, as received, is it classified as a hazardous waste? No

    • First Aid

      From MSDS Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. Skin Contact: Wash exposed area with soap and water. Get medical attention if irritation develops. Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty. Ingestion: If large amounts were swallowed, get medical advice.