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Tide Free and Gentle Liquid Laundry Detergent-12/13/2016
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: Laundry detergentStructure such as solid, liquid, aerosol etc.
Form: liquidDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: April 24, 2025P.O. Box 599
Cincinnati OH 45201
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
Advanced
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Percent of chemical in preparation.
% Conc.Purpose served by this chemical
FunctionChemical of Concern (CoC)
Chemical of Concern(CoC)Water 007732-18-5 -- Solvent No Alcohols, C10-16, ethoxylated 068002-97-1 -- Surfactant No C10-16 Alkylbenzene Sulfonic Acid 068081-81-2 -- Surfactant No MEA salts of C12-18 fatty acids 149458-07-1 -- Suds Suppresor No Sodium citrate (Trisodium citrate) 000068-04-2 -- Water Softener No Propylene glycol 000057-55-6 1.0-5.0 Solvent Yes CoC List
Ethoxylated polyethylenepolyamine 068130-99-4 -- Polymer No C10-16-Alkyldimethylamines oxides 070592-80-2 -- Surfactant No Sodium tetraborate pentahydrate 012179-04-3 1.0-5.0 Enzyme Stabilizer No Sodium cumenesulphonate 028348-53-0 -- Enzyme Stabilizer No Subtilisin (proteolytic enzyme) 009014-01-1 -- Enzyme soil remover Yes CoC List
Pancreatic Amylase 009000-90-2 -- Enzyme soil remover Yes CoC List
Mannanase, endo-1,4-beta- 037288-54-3 -- Enzyme soil remover No Sodium Formate 000141-53-7 -- Enzyme Stabilizer No (C10-C16) Alcohol ethoxylate, sulfated, sodium salt 068585-34-2 5.0-10.0 -- No C14-15 Pareth-7 068951-67-7 1.0-5.0 -- No Diethylene glycol 000111-46-6 1.0-5.0 -- No Citric acid 000077-92-9 1.0-5.0 -- No Benzenesulfonic acid, C10-C16-alkyl derivatives 068584-22-5 1.0-5.0 -- No Monoethanolamine (MEA) 000141-43-5 1.0-5.0 -- Yes CoC List
Lauric acid 000143-07-7 1.0-5.0 -- No SD Alcohol 38B 000064-17-5 1.0-5.0 -- Yes CoC List
Sulfuric acid, mono-C10-16-alkyl esters, sodium salts 068585-47-7 1.0-5.0 -- No Pentasodium pentetate 000140-01-2 0.1-1.0 -- No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID headings to sort values.
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.UN Global Harmonization Classification
Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Water 007732-18-5 231-791-2 -- -------- ------- ---- No Alcohols, C10-16, ethoxylated 068002-97-1 -- -- -------- ------- ---- No C10-16 Alkylbenzene Sulfonic Acid 068081-81-2 268-356-1 -- -------- ------- ---- No MEA salts of C12-18 fatty acids 149458-07-1 -- -- -------- ------- ---- No Sodium citrate (Trisodium citrate) 000068-04-2 200-675-3 -- -------- ------- ---- No Propylene glycol 000057-55-6 200-338-0 1.0-5.0 -------- ------- ---- No Ethoxylated polyethylenepolyamine 068130-99-4 -- -- -------- ------- ---- No C10-16-Alkyldimethylamines oxides 070592-80-2 274-687-2 -- -------- ------- ---- No Sodium tetraborate pentahydrate 012179-04-3 215-540-4 1.0-5.0 H360, H319 ------- Yes Sodium cumenesulphonate 028348-53-0 248-983-7 -- H319 P101, P102, P280, P305+P351+P338, P337+P313 No Subtilisin (proteolytic enzyme) 009014-01-1 232-752-2 -- H302, H335, H315, H318, H334, H400, H411 P260, P262, P264, P280, P285, P304+P341, P342+P311, P391 No Pancreatic Amylase 009000-90-2 232-565-6 -- H334 P260, P262, P280, P285, P304+P341, P342+P311 No Mannanase, endo-1,4-beta- 037288-54-3 253-446-5 -- H334 P261, P285, P304+P341, P342+P311 No Sodium Formate 000141-53-7 205-488-0 -- -------- ------- ---- No (C10-C16) Alcohol ethoxylate, sulfated, sodium salt 068585-34-2 500-223-8 5.0-10.0 -------- ------- ---- No C14-15 Pareth-7 068951-67-7 -- 1.0-5.0 -------- ------- ---- No Diethylene glycol 000111-46-6 203-872-2 1.0-5.0 H302 ------- No Citric acid 000077-92-9 201-069-1 1.0-5.0 H319 P264, P280, P305, P351, P338, P337, P313 No Benzenesulfonic acid, C10-C16-alkyl derivatives 068584-22-5 271-528-9 1.0-5.0 H319 P264, P280, P305+P351+P338, P337+P313 No Monoethanolamine (MEA) 000141-43-5 205-483-3 1.0-5.0 H302, H312, H332, H314, H335, H412 P273, P501 No Lauric acid 000143-07-7 205-582-1 1.0-5.0 H318 P280 No SD Alcohol 38B 000064-17-5 200-578-6 1.0-5.0 H225, H319 P210, P233, P240, P241, P242, P243, P264, P280, P303+P361+P353, P370+P378, P305+P351+P338, P337+P313, P403+P235, P501 No Sulfuric acid, mono-C10-16-alkyl esters, sodium salts 068585-47-7 -- 1.0-5.0 -------- ------- ---- No Pentasodium pentetate 000140-01-2 205-391-3 0.1-1.0 H361, H332 ------- No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Safety Data Sheet (SDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Safety Data Sheet(SDS) Date that the Safety Data Sheet (SDS) was issued by manufacturer of a specific product.
SDS DATE :December 13, 2016 Measure of Alkalinity/Acidity of substance or preparation where a level of 7 is considered as neutral.
pH Levels7.9-8.6 -
Warnings
Hazard Statements
Warning. Causes eye irritation. Combustible liquid.
Precautionary Statements
Prevention
Wash hands thoroughly after handling. Keep away from heat/sparks/open flames/hot surfaces. Keep container tightly closed. Do not eat, drink or smoke when using this product.
Response
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF SWALLOWED: Rinse mouth. DO NOT induce vomiting. Drink 1 or 2 glasses of water
In case of fire: Use water, CO2, dry chemical, or foam for extinction.
Storage
Store in a well-ventilated place. Keep cool.
Disposal
None. -
Acute health effects
From SDS:
Hazards Identification
Emergency Overview
Warning. Causes eye irritation. Combustible liquid.
Potential Health Effects
Eye Contact: Causes eye irritation.
Skin Contact: No known effect.
Inhalation: No known effect.
Ingestion: May be harmful if swallowed. -
Chronic health effects
From SDS:
No information. -
Carcinogenicity
No known effect.
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Handling information
Keep away from open flames, hot surfaces and sources of ignition. Use personal protective equipment as required. Keep container closed when not in use. Never return spills in original containers for re-use. Keep out of the reach of children. Store in a cool/low-temperature, well-ventilated, dry place away from heat and ignitionsources. -
Disposal information
Disposal should be in accordance with applicable regional, national and local laws and regulations.
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California Prop. 65 Warning
This product is not subject to warning labeling under California Proposition 65.
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First Aid
Eye Contact: Rinse with plenty of water. Get medical attention immediately if irritation persists.Skin Contact: Rinse with plenty of water. Get medical attention if irritation develops and persists.Inhalation: Move to fresh air. If symptoms persist, call a physician.Ingestion: Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately if symptoms occur.Notes to Physician: Treat symptomatically.
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