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Tide Free and Gentle Liquid Laundry Detergent-12/13/2016
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: Laundry detergentStructure such as solid, liquid, aerosol etc.
Form: liquidDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: April 24, 2025P.O. Box 599
Cincinnati OH 45201
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
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The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
Chemical Function Purpose served by this chemical.Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.California Prop.65 Chemical?The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.
UN Global Harmonization Classification
Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Endocrine Disruptor (ED)Water
Solvent
007732-18-5
231-791-2-- No -- -- -- No No Alcohols, C10-16, ethoxylated
Surfactant
068002-97-1
---- No -- -- -- No No C10-16 Alkylbenzene Sulfonic Acid
Surfactant
068081-81-2
268-356-1-- No -- -- -- No No MEA salts of C12-18 fatty acids
Suds Suppresor
149458-07-1
---- No -- -- -- No No Sodium citrate (Trisodium citrate)
Water Softener
000068-04-2
200-675-3-- No -- -- -- No No Propylene glycol
Solvent
000057-55-6
200-338-01.0-5.0 No -- -- -- No No Ethoxylated polyethylenepolyamine
Polymer
068130-99-4
---- No -- -- -- No No C10-16-Alkyldimethylamines oxides
Surfactant
070592-80-2
274-687-2-- No -- -- -- No No Sodium tetraborate pentahydrate
Enzyme Stabilizer
012179-04-3
215-540-41.0-5.0 No H360, H319 -- 
Yes No Sodium cumenesulphonate
Enzyme Stabilizer
028348-53-0
248-983-7-- No H319 P101, P102, P280, P305+P351+P338, P337+P313 
No No Subtilisin (proteolytic enzyme)
Enzyme soil remover
009014-01-1
232-752-2-- No H302, H335, H315, H318, H334, H400, H411 P260, P262, P264, P280, P285, P304+P341, P342+P311, P391 
No No Pancreatic Amylase
Enzyme soil remover
009000-90-2
232-565-6-- No H334 P260, P262, P280, P285, P304+P341, P342+P311 No No Mannanase, endo-1,4-beta-
Enzyme soil remover
037288-54-3
253-446-5-- No H334 P261, P285, P304+P341, P342+P311 No No Sodium Formate
Enzyme Stabilizer
000141-53-7
205-488-0-- No -- -- -- No No (C10-C16) Alcohol ethoxylate, sulfated, sodium salt
--
068585-34-2
500-223-85.0-10.0 No -- -- -- No No C14-15 Pareth-7
--
068951-67-7
--1.0-5.0 No -- -- -- No No Diethylene glycol
--
000111-46-6
203-872-21.0-5.0 No H302 -- No No Citric acid
--
000077-92-9
201-069-11.0-5.0 No H319 P264, P280, P305, P351, P338, P337, P313 No No Benzenesulfonic acid, C10-C16-alkyl derivatives
--
068584-22-5
271-528-91.0-5.0 No H319 P264, P280, P305+P351+P338, P337+P313 No No Monoethanolamine (MEA)
--
000141-43-5
205-483-31.0-5.0 No H302, H312, H332, H314, H335, H412 P273, P501 No No Lauric acid
--
000143-07-7
205-582-11.0-5.0 No H318 P280 No No SD Alcohol 38B
--
000064-17-5
200-578-61.0-5.0 No H225, H319 P210, P233, P240, P241, P242, P243, P264, P280, P303+P361+P353, P370+P378, P305+P351+P338, P337+P313, P403+P235, P501 
No No Sulfuric acid, mono-C10-16-alkyl esters, sodium salts
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068585-47-7
--1.0-5.0 No -- -- -- No No Pentasodium pentetate
--
000140-01-2
205-391-30.1-1.0 No H361, H332 -- No No -
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Hazard Statements
-
- Code
- Statement
- H225 : Highly flammable liquid and vapourH302 : Harmful if swallowedH312 : Harmful in contact with skinH314 : Causes severe skin burns and eye damageH315 : Causes skin irritationH318 : Causes serious eye damageH319 : Causes serious eye irritationH332 : Harmful if inhaledH334 : May cause allergy or asthma symptoms or breathing difficulties if inhaledH335 : May cause respiratory irritationH360 : May damage fertility or the unborn childH361 : Suspected of damaging fertility or the unborn childH400 : Very toxic to aquatic lifeH411 : Toxic to aquatic life with long lasting effectsH412 : Harmful to aquatic life with long lasting effects
- P101 : If medical advice is needed, have product container or label at handP102 : Keep out of reach of childrenP210 : Keep away from heat/sparks/open flames/hot surfacesP233 : Keep container tightly closedP240 : Ground/bond container and receiving equipmentP241 : Use explosion-proof electrical/ventilating/light/…/equipmentP242 : Use only non-sparking toolsP243 : Take precautionary measures against static dischargeP260 : Do not breathe dust/fume/gas/mist/vapours/sprayP261 : Avoid breathing dust/fume/gas/mist/vapours/sprayP262 : Do not get in eyes, on skin, or on clothingP264 : Wash … thoroughly after handlingP273 : Avoid release to the environmentP280 : Wear protective gloves/protective clothing/eye protection/face protectionP285 : In case of inadequate ventilation wear respiratory protectionP305 : IF IN EYES:P313 : Get medical advice/attentionP337 : If eye irritation persists:P338 : Remove contact lenses if present and easy to do. continue rinsingP351 : Rinse continuously with water for several minutesP391 : Collect spillageP303+P361+P353 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/showerP304+P341 : IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathingP305+P351+P338 : IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to doP337+P313 : Get medical advice/attentionP342+P311 : Call a POISON CENTER or doctor/physicianP370+P378 : In case of fire: Use … for extinctionP501 : Dispose of contents/container to
- GHS02 : FlammableGHS05 : CorrosiveGHS07 : IrritantGHS08 : Health HazardGHS09 : Environmentally Hazardous
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Safety Data Sheet (SDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Safety Data Sheet(SDS) Date that the Safety Data Sheet (SDS) was issued by manufacturer of a specific product.
SDS DATE :December 13, 2016 Measure of Alkalinity/Acidity of substance or preparation where a level of 7 is considered as neutral.
pH Levels7.9-8.6 -
SVHC declaration
Warning: This product contains Substances of Very High Concern (SVHC).
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Warnings
Hazard Statements
Warning. Causes eye irritation. Combustible liquid.
Precautionary Statements
Prevention
Wash hands thoroughly after handling. Keep away from heat/sparks/open flames/hot surfaces. Keep container tightly closed. Do not eat, drink or smoke when using this product.
Response
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF SWALLOWED: Rinse mouth. DO NOT induce vomiting. Drink 1 or 2 glasses of water
In case of fire: Use water, CO2, dry chemical, or foam for extinction.
Storage
Store in a well-ventilated place. Keep cool.
Disposal
None. -
Acute health effects
From SDS:
Hazards Identification
Emergency Overview
Warning. Causes eye irritation. Combustible liquid.
Potential Health Effects
Eye Contact: Causes eye irritation.
Skin Contact: No known effect.
Inhalation: No known effect.
Ingestion: May be harmful if swallowed. -
Chronic health effects
From SDS:
No information. -
Carcinogenicity
No known effect.
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Handling information
Keep away from open flames, hot surfaces and sources of ignition. Use personal protective equipment as required. Keep container closed when not in use. Never return spills in original containers for re-use. Keep out of the reach of children. Store in a cool/low-temperature, well-ventilated, dry place away from heat and ignitionsources. -
Disposal information
Disposal should be in accordance with applicable regional, national and local laws and regulations.
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California Prop. 65 Warning
This product is not subject to warning labeling under California Proposition 65.
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First Aid
Eye Contact: Rinse with plenty of water. Get medical attention immediately if irritation persists.Skin Contact: Rinse with plenty of water. Get medical attention if irritation develops and persists.Inhalation: Move to fresh air. If symptoms persist, call a physician.Ingestion: Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately if symptoms occur.Notes to Physician: Treat symptomatically.
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