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Black Flag Home Invading Spider and Scorpion Killer-Old Product
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaBlack Flag Home Invading Spider and Scorpion Killer is a powerful, effective formula that kills a variety of insects inside the home on contact. Kills bugs instantly. Kills 20 home invading spider species. Stops spiders and their webs.
Purpose of product.
Usage: Insect Repellent SprayStructure such as solid, liquid, aerosol etc.
Form: aerosolDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 13, 2024P.O. Box 142642
St. Louis MO 63114
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
Advanced
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Percent of chemical in preparation.
% Conc.Chemical of Concern (CoC)
Chemical of Concern(CoC)N-Octyl bicycloheptene dicarboximide (MGK 264) 000113-48-4 0.5 No C13-14 isoparaffin 064742-47-8 15-25 No Esfenvalerate 066230-04-4 0.05 Yes 
CoC List
Petroleum gases, liquefied, sweetened 068476-86-8 <15 Yes CoC List
Imiprothrin 072963-72-5 0.1 Yes CoC List
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Material Safety Data Sheet(MSDS) Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product.
MSDS DATE :August 28, 2008 Date when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
MSDS Verified :March 22, 2011 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATINGN N N -
Acute health effects
From MSDS:
Hazards Identification
Emergency Overview: Caution. Contents under pressure. Keep away from heat, sparks and open flame. Do not expose to temperatures above 130 degrees F (54.4 degrees C), as bursting may occur. Harmful if swallowed or absorbed through the skin. Causes moderate eye irritation. Contains petroleum distillates - Vomiting may cause aspiration pneumonia. Avoid contact with skin, eyes, and clothing. Do not puncture or incinerate container.
Potential Health Effects
Eye contact: Cause moderate eye irritation.
Skin contact: Can cause skin irritation. Can cause a burning or prickling sensation on more sensitive areas (face, eyes, mouth). Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals<15%/wt..
Skin absorption: Harmful if absorbed through the skin.
Ingestion: May be harmful if swallowed. Small amounts of this product aspirated into the respiratory system during ingestion or vomiting may cause mild to severe lung injury.
Inhalation: Excessive inhalation of mists can cause nasal and respiratory irritation. -
Chronic health effects
From MSDS:
None known. -
Carcinogenicity
None of the components present in this material at concentrations equal to or greater than 0.1 percent are listed by IARC, NTP, OSHA or ACGIH as being carcinogens.
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Handling information
Do not use or store near heat, sparks, open flame, or any other ignition sources.
Contents under pressure -DO NOT puncture or incinerate container. Do not use or store near heat, sparks, open flame, or any other ignition sources. Take prudent precautions to avoid contact with skin, eyes, and clothing. Mechanical ventilation should be used when handling this product in enclosed spaces. Do not contaminate water, food or feedstuffs by storage, handling, or disposal. Read and observe all precautions and instructions on the label.
Store containers upright and closed. Store in areas that are cool, dry, and well-ventilated. Exposure to temperatures at or above 130 degrees F (54.4 degrees C) may cause bursting. Keep away from heat, open flame, any ignition sources, and strong oxidizers. Emptied containers may retain product residues. DO NOT puncture or incinerate container.
KEEP OUT OF REACH OF CHILDREN. -
Disposal information
IF EMPTY: Place in trash or offer for recycling if available.
IF PARTLY FILLED: Call your local solid waste agency for disposal instructions. -
California Prop. 65 Warning
No information provided.
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First Aid
Eye contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
Skin contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice.
Ingestion: If swallowed immediately call a poison control center or doctor for treatment. Do not give any liquid to the person. Do not induce vomiting unless told to do so by the poison control center or doctor. Never give anything by mouth to an unconscious person.
Inhalation: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by mouth-to-mouth, if possible. Call a poison control center or doctor for further treatment advice.
Notes to Physician: For skin effects, a highly efficient therapeutic agent for pyrethrin/ pyrethroid exposure is topical application of tocopherol acetate (Vitamin E).
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UN Global Harmonization Classification
