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CPID

Health effects of consumer products

Clairol Hydrience Permanent Hair Color, Black Pearl, 52-Old Product

• Chemical Composition/Ingredients

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

  Advanced
  Primary Chemical Name is the standard name assigned to a chemical substance. Chemical	Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.  CAS No./ID	Percent of chemical in preparation. % Conc.		Chemical of Concern (CoC) Chemical of Concern(CoC)
  3-Aminophenol	000591-27-5	Colorant		No
  Ammonium hydroxide	001336-21-6	Colorant		Yes  NY-23: AOEC Asthmagens  CoC List
  Behentrimonium chloride	017301-53-0	Colorant		Yes  NY-20:CA Environmental Biocontaminant Monitoring Program Priority Chemical CA-21-California Environmental Biocontaminant Monitoring Program Priority Chemicals  CoC List
  Benzyl alcohol	000100-51-6	Conditioner		Yes  NY-22: EU Fragrance Allergen CA-24-EU Fragrance Allergens  CoC List
  C12-15 Pareth-3	068131-39-5	Colorant		No
  Carmine	001260-17-9	Colorant		No
  Ceteareth 80	068439-49-6	Developer		No
  Cetostearyl alcohol	067762-27-0	Developer		No
  Cetyl alcohol	036653-82-4	Conditioner		Yes  NY-24: U.S. EPA TSCA Chemical of Concern  CoC List
  Cocamide MEA	068140-00-1	Colorant		No
  Cyclopentasiloxane, 2,4,6,8,10-pentamethyl-	006166-86-5	Conditioner		No
  Dilinoleic acid	006144-28-1	Colorant		No
  Dimethicone	009006-65-9	Conditioner		No
  Ethylenediaminetetraacetic acid (EDTA)	000060-00-4	Colorant		No
  Ethylenediaminetetraacetic acid (EDTA)	000060-00-4	Colorant		No
  Etidronic acid	002809-21-4	Developer		No
  Fragrance(s)/perfume(s)	000000-00-1	Colorant		No
  Fragrance(s)/perfume(s)	000000-00-1	Colorant		No
  Fucus Vesiculous Extract	068917-51-1	Colorant		No
  Glutamic Acid	000056-86-0	Conditioner		No
  Hydrogen peroxide	007722-84-1	Developer		Yes  NY-23: AOEC Asthmagens  CoC List
  Iron oxide(s) (unspecified)	999999-60-2	Colorant		No
  Isoascorbic acid	000089-65-6	Colorant		No
  Laureth-23	009002-92-0	Developer		No
  Linoleamidopropyl dimethylamine dimer dilinoleate	125804-10-6	Colorant		No
  Methylchloroisothiazoline	026172-55-4	Conditioner		No
  Methylisothiazoline	002682-20-4	Conditioner		No
  Mica	012001-26-2	Colorant		No
  N,N-bis(2-Hydroxyethyl)-p-phenylenediamine sulfate	063886-75-9	Colorant		No
  Oleth-10	024871-34-9	Colorant		No
  p-Phenylenediamine	000106-50-3	Colorant		Yes  NY-17: California Toxic Air Contaminant Chemicals (TACs) CA-18-California Toxic Air Contaminant Chemicals (TACs) MN-01-Minnesota Toxic Free Kids, CHC  CoC List
  Panthenol	000081-13-0	Conditioner		No
  Panthenyl ethyl ether	000667-83-4	Conditioner		No
  Polyquaternium-22	053694-17-0	Colorant		No
  Polyquaternium-37	026161-33-1	Developer		No
  Propylene glycol dicaprylate/dicaprate	009062-04-8	Developer		No
  Resorcinol	000108-46-3	Colorant		Yes  MN-01-Minnesota Toxic Free Kids, CHC  CoC List
  Sodium metasilicate	006834-92-0	Colorant		No
  Sodium sulfite	007757-83-7	Colorant		No
  Sorbitol	000050-70-4	Colorant		No
  Stearamidopropyl dimethylamine	007651-02-7	Conditioner		No
  Steareth-21	009005-00-9	Colorant		No
  Steareth-21	009005-00-9	Colorant		No
  Stearyl alcohol	000112-92-5	Conditioner		No
  Styrene/PVP copolymer	025086-29-7	Developer		No
  Titanium dioxide	013463-67-7	Colorant		Yes  NY-08: IARC Group 1, 2A & 2B Carcinogens CA-09-IARC Group 1, 2A & 2B Carcinogen MN-01-Minnesota Toxic Free Kids, CHC  CoC List
  Trideceth-12	024938-91-8	Developer		No
  Water	007732-18-5	Developer		No
  Water	007732-18-5	Colorant		No
  Water	007732-18-5	Colorant		No
   
  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID headings to sort values.
  

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers. 

  CAS No./ID

  Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
  EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
  ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
  NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-x

  EC No.

  Percent of chemical in preparation.

  % Conc.

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

   UN Global Harmonization Classification

  Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:

  • Physical Hazard Codes (H200 series)
  • Health Hazard Codes (H300 series)
  • Environmental Hazard Codes (H400 series)
  • Supplementary Hazard Codes (EUH series)

  Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Hazard Statement Code

  Precautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
  Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Precautionary Code

  Pictogram

  SVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
  1.  Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
  2.  Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
  3.  Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).

  SVHC?

  3-Aminophenol	000591-27-5	209-711-2	Colorant	H411, H400, H317, H302, H332 P264, P270, P301+P312, P330, P261, P271 No
  Ammonium hydroxide	001336-21-6	215-647-6	Colorant	H314, H335, H400 P260, P280, P301+P330+P331, P305+P351+P338, P391, P501 No
  Behentrimonium chloride	017301-53-0	241-327-0	Colorant	-------- ------- ---- No
  Benzyl alcohol	000100-51-6	202-859-9	Conditioner	H302, H332 ------- No
  C12-15 Pareth-3	068131-39-5	500-195-7	Colorant	-------- ------- ---- No
  Carmine	001260-17-9	215-023-3	Colorant	-------- ------- ---- No
  Ceteareth 80	068439-49-6	939-518-5	Developer	-------- ------- ---- No
  Cetostearyl alcohol	067762-27-0	267-008-6	Developer	-------- P101, P102, P280, P301+P312, P302+P352, P305+P351+P338 ---- No
  Cetyl alcohol	036653-82-4	253-149-0	Conditioner	-------- ------- ---- No
  Cocamide MEA	068140-00-1	268-770-2	Colorant	-------- ------- ---- No
  Cyclopentasiloxane, 2,4,6,8,10-pentamethyl-	006166-86-5	228-204-7	Conditioner	H226 P210, P243, P403+P235 No
  Dilinoleic acid	006144-28-1	--	Colorant	-------- ------- ---- No
  Dimethicone	009006-65-9	--	Conditioner	-------- ------- ---- No
  Ethylenediaminetetraacetic acid (EDTA)	000060-00-4	200-449-4	Colorant	H319 ------- No
  Ethylenediaminetetraacetic acid (EDTA)	000060-00-4	200-449-4	Colorant	H319 ------- No
  Etidronic acid	002809-21-4	220-552-8	Developer	H290, H318, H302 P234, P390, P406, P280, P305+P351+P338, P310, P264, P270, P301+P312, P330, P501 No
  Fragrance(s)/perfume(s)	000000-00-1	--	Colorant	-------- ------- ---- No
  Fragrance(s)/perfume(s)	000000-00-1	--	Colorant	-------- ------- ---- No
  Fucus Vesiculous Extract	068917-51-1	295-780-4	Colorant	-------- ------- ---- No
  Glutamic Acid	000056-86-0	200-293-7	Conditioner	-------- ------- ---- No
  Hydrogen peroxide	007722-84-1	231-765-0	Developer	H271, H302, H314, H332, H335, H412 ------- No
  Iron oxide(s) (unspecified)	999999-60-2	--	Colorant	-------- ------- ---- No
  Isoascorbic acid	000089-65-6	201-928-0	Colorant	-------- ------- ---- No
  Laureth-23	009002-92-0	500-002-6	Developer	-------- ------- ---- No
  Linoleamidopropyl dimethylamine dimer dilinoleate	125804-10-6	--	Colorant	-------- ------- ---- No
  Methylchloroisothiazoline	026172-55-4	247-500-7	Conditioner	-------- ------- ---- No
  Methylisothiazoline	002682-20-4	220-239-6	Conditioner	H301, H311, H314, H330, H317, H410, EUH071 ------- No
  Mica	012001-26-2	-	Colorant	-------- ------- ---- Yes
  N,N-bis(2-Hydroxyethyl)-p-phenylenediamine sulfate	063886-75-9	--	Colorant	-------- ------- ---- No
  Oleth-10	024871-34-9	--	Colorant	-------- ------- ---- No
  p-Phenylenediamine	000106-50-3	203-404-7	Colorant	H301, H311, H331, H370, H319, H317, H410 P264, P270, P273, P311, P321, P391, P403+P233, P405, P501, P301+P310, P330, P305+P351+P338, P337+P313, P272, P302+P352, P333+P313, P363 No
  Panthenol	000081-13-0	201-327-3	Conditioner	-------- ------- ---- No
  Panthenyl ethyl ether	000667-83-4	211-569-1	Conditioner	-------- ------- ---- No
  Polyquaternium-22	053694-17-0	-	Colorant	-------- ------- ---- Yes
  Polyquaternium-37	026161-33-1	-	Developer	-------- ------- ---- Yes
  Propylene glycol dicaprylate/dicaprate	009062-04-8	--	Developer	-------- ------- ---- No
  Resorcinol	000108-46-3	108-46-3	Colorant	H302, H315, H319, H400 ------- No
  Sodium metasilicate	006834-92-0	229-912-9	Colorant	H290, H314, H335 P261, P262, P280, P301+P330+P331, P303+P361+P353, P305+P351+P338 No
  Sodium sulfite	007757-83-7	231-821-4	Colorant	-------- ------- ---- No
  Sorbitol	000050-70-4	200-061-5	Colorant	-------- ------- ---- No
  Stearamidopropyl dimethylamine	007651-02-7	231-609-1	Conditioner	H318, H400, H411 P280, P305+P351+P338, P310, P273, P391, P501 No
  Steareth-21	009005-00-9	500-017-8	Colorant	-------- ------- ---- No
  Steareth-21	009005-00-9	500-017-8	Colorant	-------- ------- ---- No
  Stearyl alcohol	000112-92-5	204-017-6	Conditioner	-------- ------- ---- No
  Styrene/PVP copolymer	025086-29-7	--	Developer	-------- ------- ---- No
  Titanium dioxide	013463-67-7	236-675-5	Colorant	-------- ------- ---- No
  Trideceth-12	024938-91-8	-	Developer	-------- ------- ---- Yes
  Water	007732-18-5	231-791-2	Developer	-------- ------- ---- No
  Water	007732-18-5	231-791-2	Colorant	-------- ------- ---- No
  Water	007732-18-5	231-791-2	Colorant	-------- ------- ---- No

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID or EC No. headings to sort values.
  

   

  Sources for Chemical Classifications

  • European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
  • European Chemicals Agency, http://echa.europa.eu/
       ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
• • Health Effects Information

    • Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.

    • Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product. MSDS DATE :

      February 14, 2002

    • 	Health	Flammability	Reactivity
      HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product. HMIS RATING	N	N	N

    • Warnings

      This product contains ingredients that may cause skin irritation on certain individuals, and a preliminary test according to accompanying directions should first be made. This product must not be used for dyeing the eyelashes or eyebrows; to do so may cause blindness.

    • Acute health effects

      From MSDS HEALTH HAZARDS AND HAZARD DATA FOR THE COLORANT-(MSDS 2/14/02) The TLV of the mixture has not been established. EYE CONTACT: CAUTION. Unmixed oxidation haircolors are eye irritants. When oxidation haircolors are mixed with developers (hydrogen peroxide), the mixture may cause severe irritation and possible permanent eye injury. SKIN CONTACT: May cause skin irritation or sensitization in sensitive individuals. INHALATION: Inhalation of ammonia vapors may result in respiratory irritation. INGESTION: Moderately toxic. ROUTE OF ENTRY Inhalation: Yes; Ingestion: Yes; Skin: Yes. Pre-existing dermatitis would likely be made worse by exposure to these products. Bronchitis may be aggravated by irritant vapors. HEALTH HAZARDS AND HAZARD DATA FOR THE DEVELOPER-(MSDS 9/4/01) The TLV of the mixture has not been established. EYE CONTACT: CAUTION. Developers are eye irritants. May cause severe irritation and possible permanent eye injury. SKIN CONTACT: Prolonged contact with skin may bleach it and cause burns. INHALATION: Not likely to be inhaled. INGESTION: Moderately toxic. ROUTE OF ENTRY Inhalation: No; Ingestion: Yes; Skin: Yes. Pre-existing dermatitis would likely be made worse by exposure to these products. HEALTH HAZARDS AND HAZARD DATA FOR THE CONDITIONER-(MSDS 9/4/01) The TLV of the mixture has not been established. EYE CONTACT: Potential eye irritant. SKIN CONTACT: Potential skin irritant. INHALATION: Not applicable. INGESTION: Practically non toxic. ROUTE OF ENTRY Inhalation: No; Ingestion: Yes; Skin: Yes. Pre-existing dermatitis would likely be made worse by exposure to these products.

    • Chronic health effects

      From MSDS HAZARD DATA FOR THE COLORANT A composite mixture of oxidative dyes has been tested in prolonged topical exposure studies of laboratory animals. No adverse effects on growth, reproduction or general health were observed. In topical studies no target organ toxicity was observed other than limited effect on treated skin. Pre-existing dermatitis would likely be made worse by exposure to these products. Bronchitis may be aggravated by irritant vapors. HAZARD DATA FOR THE DEVELOPER When developers were mixed with hair dyes and applied to the skin of animals for prolonged periods, no adverse effects on growth, reproduction or general health were observed. Prolonged contact with skin may result in bleaching and irritation of skin. Target Organs: Skin Pre-existing dermatitis would likely be made worse by exposure to these products. HAZARD DATA FOR THE CONDITIONER For purposes of chronic exposure under the OSHA Hazard Communication Standard, this is an untested mixture. These products have been used extensively by consumers and Worldwide Beauty Care is not aware of any significant adverse effects. Target Organs: These products contain ingredients which have been shown to affect tissues or organs when fed at high levels of exposure in animal studies not encountered in normal use. Target Organs identified in animal studies are as follows: Glycerin:- Kidney, Liver; Propylene Glycol:- CNS; Isopropyl Alcohol:- CNS. Pre-existing dermatitis would likely be made worse by exposure to these products.

    • Carcinogenicity

      From MSDS Not listed as carcinogen by NTP, IARC or OSHA.

    • Handling information

      From MSDS COLORANT Do not expose to sunlight. Keep away from radiators and heat. Do not store any haircolor after it has been mixed with developer. Decomposition of hydrogen peroxide may occur with increase in pressure and possible container rupture. DEVELOPER Keep in cool place. Avoid contamination. Keep closed when not in use. Store in the original tightly capped containers away from sunlight, heat sparks and flame. Do not store any tint, lightener, lotion or bleach powder after it has been mixed with developer; container may rupture. Never return unused material to original container. Empty containers should be rinsed with water before discarding. Keep out of reach of children. Other precautions: Decomposition of hydrogen peroxide may occur with increase in pressure and possible container rupture. CONDITIONER No precautions necessary.

    • Disposal information

      From MSDS Products covered by this MSDS, in their original form, are considered non-hazardous waste according to RCRA. Additionally, disposal should be in accordance with all applicable Local, State and Federal regulations.

    • First Aid

      From MSDS Eye Contact: Remove contact lenses, if used. Flush immediately with plenty of water for 15 minutes. Get medical attention IMMEDIATELY. Skin Contact: If spilled, wash skin immediately with soap and water (do not use solvents). Change into clean clothing. If skin irritation or sensitization develops, contact dermatologist. Inhalation: Remove person to fresh air. Increase ventilation. Ingestion: Rinse out mouth with water and administer large amounts of milk. Contact Poison Control Center.